We report the first spectroscopic identification of massive Galactic asymptotic giant branch (AGB) stars at the beginning of the thermal pulse (TP) phase. These stars are the most Li-rich massive AGBs found to date, super Li-rich AGBs with logε(Li)∼3-4. The high Li overabundances are accompanied by weak or no s-process element (i.e. Rb and Zr) enhancements. A comparison of our observations with the most recent hot bottom burning (HBB) and s-process nucleosynthesis models confirms that HBB is strongly activated during the first TPs but the 22 Ne neutron source needs many more TP and third dredge-up episodes to produce enough Rb at the stellar surface. We also show that the short-lived element Tc, usually used as an indicator of AGB genuineness, is not detected in massive AGBs which is in agreement with the theoretical predictions when the 22 Ne neutron source dominates the s-process nucleosynthesis.

The presence of short-lived (∼ Myr) radioactive isotopes in meteoritic inclusions at the time of their formation represents a unique opportunity to study the circumstances that led to the formation of the Solar System. To interpret these observations we need to calculate the evolution of radioactive-to-stable isotopic ratios in the Galaxy. We present an extension of the open-source galactic chemical evolution codes NuPyCEE and JINAPyCEE that enables to track the decay of radioactive isotopes in the interstellar medium. We show how the evolution of isotopic ratio depends on the star formation history and efficiency, star-to-gas mass ratio, and galactic outflows. Given the uncertainties in the observations used to calibrate our model, our predictions for isotopic ratios at the time of formation of the Sun are uncertain by a factor of 3.6. At that time, to recover the actual radioactive-to-stable isotopic ratios predicted by our model, one can multiply the steady-state solution (see Equation 1) by 2.3 +3.4 −0.7 . However, in the cases where the radioactive isotope has a half-life longer than ∼ 200 Myr, or the target radioactive or stable isotopes have mass-and/or metallicity-depended production rates, or they originate from different sources with different delay-time distributions, or the reference isotope is radioactive, our codes should be used for more accurate solutions. Our preliminary calculations confirm the dichotomy between radioactive nuclei in the early Solar System with r-and s-process origin, and that 55 Mn and 60 Fe can be explained by galactic chemical evolution, while 26 Al cannot.