Micro- and nano-sensors lie at the heart of critical innovation in fields ranging from medical to environmental sciences. In recent years, there has been a significant improvement in sensor design along with the advances in micro- and nano-fabrication technology and the use of newly designed materials, leading to the development of high-performance gas sensors. Advanced micro- and nano-fabrication technology enables miniaturization of these sensors into micro-sized gas sensor arrays while maintaining the sensing performance. These capabilities facilitate the development of miniaturized integrated gas sensor arrays that enhance both sensor sensitivity and selectivity towards various analytes. In the past, several micro- and nano-gas sensors have been proposed and investigated where each type of sensor exhibits various advantages and limitations in sensing resolution, operating power, response, and recovery time. This paper presents an overview of the recent progress made in a wide range of gas-sensing technology. The sensing functionalizing materials, the advanced micro-machining fabrication methods, as well as their constraints on the sensor design, are discussed. The sensors’ working mechanisms and their structures and configurations are reviewed. Finally, the future development outlook and the potential applications made feasible by each category of the sensors are discussed.
Quartz Crystal Microbalance (QCM) is a candidate technology for high sensitivity application. This mass sensor's property depends on the piezoelectric property of the AT-cut quartz crystal. QCM has been widely employed for gas detection due to its comparative advantages including high mass sensitivity, potential for array configuration, low cost, ease of fabrication as well as wide range of available sensitive material compatibility. However, its application has been limited due to two main disadvantages of the nonuniform mass sensitivity across the electrodes and lower frequency of operation. In this work, in order to overcome these disadvantages, a novel concentric electrode structure combined with the dual inverted mesa structure has been proposed and implemented. It is demonstrated that the developed and optimized concentric electrode has provided a uniform displacement across the QCM's sensing electrode. In addition, the dual inverted mesa design has been implemented in the QCM array in which a high fundamental resonant frequency of 33 MHz has been achieved without interference between the adjacent channels in the sensor array. The interference between the adjacent high frequency QCM channels has been eliminated and therefore, each QCM can function as an individual gas sensor when coated with the designed sensing layers. For 33 MHz, the interference has been eliminated at the optimal center to center between electrode distance (c2c). In the case of 10 MHz array, c2c value of 6 mm is achieved which is lower than the value of c2c achieved on a traditionally un-etched QCM array which was found equal to 6.5 mm. Therefore, the proposed QCM array design is shown to reduce the overall size while enhancing the device sensitivity, uniformity and performance. INDEX TERMS Array configuration, concentric electrode, dual inverted mesa structure, frequency interference, high frequency, micromachining, piezoelectric resonator, quartz crystal microbalance, QCM, uniform displacement profile.
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