Recovery of moderately viscous oils (below 2000 mPaS) from reservoirs which are unsuitable for thermal treatment may be possible by non-thermal methods. This paper addresses this problem within the framework of field and laboratory experience. Many heavy oil reservoirs in Canada fit this category: they are too thin, deep, or oil saturation is low, or have other undesirable features for a thermal recovery method to be successful. The non-thermal recovery methods considered are: improved waterfloods, polymer flooding, surfactant, caustic and other chemical floods, immiscible carbon dioxide flooding, solvent flooding, etc. Ranges in oil recovery as based upon field experience and from laboratory experiments are indicated. It is shown that non-thermal methods may be successful for heavy oil recovery under rather restrictive conditions. Based upon the data from some 113 field tests, it seems that immiscible carbon dioxide floods are more likely to be successful. In nearly all cases, the oil recovery is much lower than that attainable by thermal methods. This paper concludes with an evaluation of non-thermal recovery methods. Introduction Heavy oil deposits in Canada, Venezuela and the United States comprise several trillion barrels. Thermal methods, viz. steam injection and in situ combustion are best for recovering some of this oil, provided that the reservoir conditions are favourable. However, over half of the oil occurs in reservoirs that are not suitable for thermal methods. This is the case when the formations are thin (< 10 m), depths are large (> 1000m), formation permeability is too low to permit high enough injection rates, or the oil saturation is low, perhaps combined with a low porosity. Under such conditions, a non-thermal recovery method may be employed, which may be further modified for a viscous oil. Such methods would be expected to be applicable to moderately viscous oils (viscosity less than a thousand mPas), if the remaining conditions are favourable. This paper reviews alkaline flooding, polymer flooding, immiscible carbon dioxide flooding in detail, and discusses other non-thermal methods briefly. Results of laboratory investigations are discussed alongside field tests. Comprehensive tables list the laboratory data for all processes, as well as field data for each process tested. It is believed that the data presented would help in assessing non-thermal recovery methods for a specific reservoir. Furthermore, the laboratory data summarized provide an idea of the range of variability of results, and a comparison with the field recovery values underscores the problems associated with unscaled experiments. Problems in Viscous Oil Recovery The principal difficulty in the recovery of heavy oils is the high oil viscosity, leading to low oil mobility, which makes displacement by a cheap fluid, such as water or gas, inefficient on account of the "unfavourable" mobility ratio (i.e. mobility of the displacing fluid is greater than the mobility of the displaced oil). Under suitable reservoir conditions this may be corrected by the use of heat. However, this may be impractical for a variety of reasons, some of which were mentioned above.
The compressibility factor of natural gases is necessary in many petroleum engineering calculations. Some of these calculations are the following: evaluation of a newly discovered formation, pressure drop from flow of gas through a pipe, pressure gradient in gas wells, gas metering, gas compression, and processing. Typically, the gas compressibility factor is measured by laboratory experiments. These experiments are expensive and time-consuming. Occasionally, experimental data became unavailable and the gas compressibility factor is estimated from correlations using gas composition or gas gravity. This paper presents new methods for calculating the gas compressibility factors for gas condensates at any temperature and pressure. The method is based on compositional analysis of 1200 compositions of gas condensates collected worldwide. When the gas composition is known, this study presents a simple mixing rule to calculate the pseudo-critical properties of the gas condensate. The new mixing rule accounts for the presence of the heptane plus fraction and none hydrocarbons. In case the gas composition is unavailable, the study presents a new gas gravity correlation to estimate pseudo-critical properties of the gas condensate. This study also presents an evaluation of eight methods to characterize the plus fraction, three widely used mixing rules, and six methods to calculate the gas compressibility factor. Thus, this study presents an evaluation of one hundred forty-four possible methods of calculating the gas compressibility factor for gas condensates. The accuracy of the new mixing rule and the gas gravity correlation has been compared to other published methods. The comparison indicates that the proposed methods are consistent and provide accurate results.
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