The driving idea and the main objective of this synthetic work is the study of physicochemical factors such as the dielectric constant of the solvent, the polarizability of the chains and the Gap energy of the conductive polymers, these characteristics condition their properties. electrical and electrochemical. We focused our study on polyaniline, two synthetic methods are presented: chemical polymerization and electropolymerization with emphasis on the theoretical aspects of the phenomena involved as well as on the electrochemical methods used such as cyclic voltammetry. We have therefore developed with maximum clarity the links existing between the physico-chemical properties of polyaniline and its electrical conductivity.