Ethylene is considered the most important petrochemical constituent in the world today. It is currently produced via the thermal cracking process, which is generally expensive. Ethane dehydrogenation (EDH) is endothermic, and the thermodynamic equilibrium limits its conversion. The present study explores the viability of using a catalytic membrane reactor (MR) for ethylene production from EDH. The removal of hydrogen from the reaction zone using a palladium–silver (Pd–Ag) membrane has led to a high shift in the equilibrium conversion. The effects of operating conditions and reactor configurations on the ethane conversion were investigated. The ultimate ethane conversion was 22.2% when using the MR at 660 K and 300 kPa. The ethane conversion in the shell-side of the reactor increased to ∼99% when benzene hydrogenation was added as an auxiliary reaction in the tube-side of the reactor. Two new processes for ethylene production were developed for an annual capacity of 100,000 metric tons. Cryogenic distillation was required to separate ethylene from ethane if there is no auxiliary reaction. On the other hand, the ethylene process with cyclohexane as a byproduct does not require a refrigeration cycle system, and its economic analysis shows a return on investment of 34.4%, indicating that the process is a promising technology.

Butyl acetate (BuAc) is widely used as a solvent in many applications, mainly in the food and pharmaceutical industries. The conventional process for BuAc production is both capital and energy intensive. The purification process involves the separation of BuAc from the azeotropic mixture of water and n-butanol, which is difficult to accomplish using a simple distillation unit. In this study, a membrane reactor (MR) for BuAc production via the esterification of n-butanol was investigated. The MR using the Amberlyst-15 catalyst was modeled and validated with previously reported experimental data, and a good agreement was achieved. The ultimate conversion of n-butanol using the MR was 92.0%, compared to 69.8% for the conventional reactor. This study is the first to propose an intensified MR-based process for butyl acetate production. The MR-based process was developed and rigorously simulated using Aspen Plus for an annual plant capacity of 92,500 metric tons of BuAc. The MR-based process is environmentally friendly regarding CO2 emissions, with a reduction of 80% compared to the conventional process. The economic analysis of the MR-based process shows a payback period of 2.7 years and a return on investment (ROI) of 23.1%. The MR-based process for BuAc production is a promising technology that provides similar key benefits as compared to the reactive distillation (RD) process.