The effect of different content (0–20 wt%) Acrylonitrile-styrene-acrylic (ASA) on mechanical, thermal and three-body wear behaviors of eucalyptus fiber/polyvinyl chloride (EF/PVC) composites were studied in this research. The results show that the mechanical properties of the composites such as impact strength, tensile strength, flexural strength and flexural modulus increased with increasing ASA content lower than 15 wt%. The addition of 15 wt% and 20 wt% ASA can improve thermal stability of the EF/PVC composites in the early period of the heating, and the effect weakened on later stage due to the thermal degradation of ASA, which occurred in the temperature range 416°C–442°C. The three-body wear resistance of the EF/PVC composites can be improved by ASA, and the abrasive wear mechanism of the composites was predominated by linear travel, sand particle plough and cut action, ASA and PVC plastic deformation, and fibers debonding.

Wood-plastic composites are being widely used more and more, and the bonding strength between fillers and matrix is an important factor affecting the properties of wood-plastic composites. In this study, rapeseed straw and rapeseed stalk were pretreated with sodium hydroxide and then filled with polyvinyl chloride matrix to prepare composites. The chemical composition, thermal stability, microstructure, physical properties, mechanical properties, and abrasive wear resistance of the composites were characterized, and the effects of different concentrations of alkaline treatment on rapeseed straw composite and rapeseed stalk composite were revealed. The results show that alkaline treatment has no significant effect on the chemical composition of the composites but has an obvious effect on other properties. Among them, after 1% alkaline treatment, rapeseed straw composite has the highest hardness, thermal stability, and impact strength, rapeseed stalk composite has the highest impact strength and bending strength. After 3% alkaline treatment, rapeseed straw composite has more wear resistance, rapeseed stalk composite has the highest density, the highest tensile strength, and more wear resistance. The rapeseed straw composite with 5% alkaline treatment has the highest density, and the rapeseed stalk composite with 7% alkaline treatment has the highest thermal stability. The hardness of rapeseed stalk composite and the tensile strength and bending strength of rapeseed straw composite decreased with the increase of alkaline treatment concentration.