We report a field study of soil gas transport of volatile organic compounds (VOCs) into a slab-on-grade building found at a site contaminated with gasoline. Although the high VOC concentrations (30-60 g nr 3 ) measured in the soil gas at depths of 0.7 m below the building suggest a potential for high levels of indoor VOC, the measured indoor air concentrations were lower than those in the soil gas by approximately six orders of magnitude (~ 0.03 mg nr 3 ). This large ratio is explained by 1) the expected dilution of soil gas entering the building via ambient building ventilation (a factor of ~ 1000), and 2) an unexpectedly sharp gradient in soil gas VOC concentration between the depths of 0.1 and 0.7 m (a factor of ~ 1000). Measurements of the soil. physical and biological characteristics indicate that a partial physical barrier to vertical transport in combination with microbial degradation provides a likely explanation for this gradient. These factors are likely to be important to varying degrees at other sites.
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