Therapeutic study, level IV.

No abstract

Achieving mobility control of steam in porous media has been approached by the implementation of foaming surfactant additives; however, foam generated with surfactants lack stability at high temperatures (≥ 200 °C). In this study, a nanofluid was formulated for steam co-injection to address common issues with surfactants as steam additives. The nanofluids were formulated using synergistic interaction of nanoparticles and surfactants (both readily available) to address thermal stability, and foam stability at the conditions encountered in thermal enhanced oil recovery processes such as steam assisted gravity drainage. Zeta potential analysis, static tests, and high temperature aging tests were performed to obtain the ideal mixture of nanoparticles and surfactants. A steam/foam core flooding apparatus was used to evaluate the mobility reduction of nanofluids using multiple differential pressure transmitters situated along the length of a 40 cmsand pack to confirm foam propagation. The tests were first conducted at 200 °C with nitrogen as a non-condensable gas carrier. Upon confirming nanofluid mobility reduction characteristics at 200 °C with gas, a successful nanofluid was co-injected with superheated steam at backpressure corresponding to a saturation temperature of 200 °C inside an oven with that set point. Mobility reduction characteristics were obtained for each formulation by normalizing the differential pressure of additive multiphase flow to their respective baselines. Statictests and high-temperature core floods demonstrated a strong synergy between appropriate combinations of surfactants and nanoparticles.None of thesurfactants and nanoparticlesyielded mobility reduction when used on their own; however, when selected according to a design basis, nanoparticle/surfactant mixtures exhibit strong mobility control with steam as well as hot gas. The foam produced in the porous media was held in a visual cellat 150 °C for 24 h with no loss in foam height. Furthermore, foam generated with the nanoparticle-surfactant hybrid remained stable in static tests in the presence of heavy crude oil for more than one week. The primary novelty of this study is the ability to use less exotic surfactants and nanoparticles as steam mobility control agents, increased foam stability in the presence of oil, and demonstrable synergy between commodity molecules (i.e., surfactant) and nanoparticles at steam flooding conditions. The successful additive mixture was developed with scalability in mind such that manufacturing will not hinder the feasibility of scale-up for industrial use.

Understanding fluid flow in porous media is essential with complex and multiphase fluid flow. We demonstrate that high-resolution in-line density measurements are a valuable tool in this regard. An in-line densitometer is used in fluid flow in porous media applications to quantify fluid production and obtain quantitative and qualitative information such as breakthrough times, emulsion/foam generation, and steam condensation.In order to determine the potential applications for in-line densitometry for fluid flow in porous media, a series of sand pack floods were performed with a densitometer placed at the outlet of a sand pack. All fluids passed through the measurement cell at experiential temperatures and pressures. An algorithm was developed and applied to the density data to provide a quantitative determination of oil and water production. The second series of tests were performed at high temperature and pressure, with a densitometer placed at the inlet and outlet of a sand pack, for steam applications. In both series of experiments, data acquisition was collected at 1 hertz and the analyzed density data was compared to results from the conventional effluent analysis, including Dean-Stark, toluene separations, magnetic susceptibility measurement, and flash calculations where applicable.The high-resolution monitoring of effluent from a flow experiment through porous media in a system with two phases of known densities enables two-phase production to be accurately quantified in the case of both light and heavy oil. The frequency of measurements results in a high-resolution history of breakthrough times and fluid behavior. In the case of monitoring steam injection processes, reliable laboratory tests show that in-line density measurements enable the determination of steam quality at the inlet and outlet of a sand pack and qualitative determination of steam condensation monitoring The use of in-line densitometry provides insight on the monitoring of complex fluid flow in porous media, which typical bulk effluent analysis is not able to do. The ability to measure produced fluids at high resolution and extreme temperatures reduces mass balance error associated with the effluent collection and broadens our understanding of complex fluid flow in porous media.Olsen et al. (2017) described a method for using a densitometer for quantifying oil production in two-E3S Web of Conferences 146, 01005 (2020)