In this work, based on the thermodynamic prediction, the comprehensive studies of the influence of Cu for Fe substitution on the crystal structure and magnetic properties of the rapidly quenched Fe85B15 alloy in the ribbon form are performed. Using thermodynamic calculations, the parabolic shape dependence of the ΔGamoprh with a minimum value at 0.6% of Cu was predicted. The ΔGamoprh from the Cu content dependence shape is also asymmetric, and, for Cu = 0% and Cu = 1.5%, the same ΔGamoprh value is observed. The heat treatment optimization process of all alloys showed that the least lossy (with a minimum value of core power losses) is the nanocomposite state of nanocrystals immersed in an amorphous matrix obtained by annealing in the temperature range of 300–330 °C for 20 min. The minimum value of core power losses P10/50 (core power losses at 1T@50Hz) of optimally annealed Fe85-xCuxB15 x = 0,0.6,1.2% alloys come from completely different crystallization states of nanocomposite materials, but it strongly correlates with Cu content and, thus, a number of nucleation sites. The TEM observations showed that, for the Cu-free alloy, the least lossy crystal structure is related to 2–3 nm short-ordered clusters; for the Cu = 0.6% alloy, only the limited value of several α-Fe nanograins are found, while for the Cu-rich alloy with Cu = 1.2%, the average diameter of nanograins is about 26 nm, and they are randomly distributed in the amorphous matrix. The only high number of nucleation sites in the Cu = 1.2% alloy allows for a sufficient level of grains’ coarsening of the α-Fe phase that strongly enhances the ferromagnetic exchange between the α-Fe nanocrystals, which is clearly seen with the increasing value of saturation induction up to 1.7T. The air-annealing process tested on studied alloys for optimal annealing conditions proves the possibility of its use for this type of material.
Building energy efficiency has grown strong in a context of soaring energy prices, especially in Europe. The use of energy-saving devices strongly influences its improvement, but in many cases, it is far from sufficient., especially if the energy comes from renewable sources with forced production. In the case of buildings, these are usually photovoltaic (PV) sources. For this reason, energy management systems (EMS) are becoming increasingly popular as they allow the increase in self-consumption and reduce the size of energy storage. This article presents analyses of historical energy consumption profiles in selected small- and medium-sized buildings powered by renewable energy sources. The implementation limitations of this type of systems, depending on the profile of the building, were identified and guidelines were presented to assess low-cost solutions dedicated to small buildings and considering the actual conditions of existing systems. Statistical analyzes were conducted for the energy demand profiles of 15 different buildings. The analyzes consisted of the preparation of box plots for each hour of working days and the calculation of the relative standard deviation (RSD) index for annual profiles of 60 min periods. The analyzes showed that the RSD index has low values for commercial buildings (e.g., hospital 7% and bank 15%) and very high values for residential buildings—even over 100%. On this basis, it can be concluded about the usefulness of energy profiles for demand forecasting. The novelty of the proposed method is to examine the possibility of using measurement data as data to forecast energy consumption based on statistical analysis, dedicated to low-cost EMS system solutions.
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