Although chemiluminescent reactions
are generally used in demonstrations to pique students’ interest
in chemistry, they may serve as a great tool for studying reaction
kinetics. In this paper, we briefly present an overview of the basics
of chemiluminescent kinetics and introduce a safe and robust formulation
for making chemiluminescent reactions using citrate-based solvents
suitable for chemical studies. The rates of chemiluminescence reactions
were quantified using open-source Arduino-development-board projects
and ubiquitous photoresistor-based sensors. The simple and versatile
formulation as well as the data logging proposed in this work provide
instructors with an easy, interesting, and cost-effective tool for
teaching reaction kinetics at room temperature. The experiment can
be tuned to accommodate for time constraints and various levels of
complexity in postprocessing. On the basis of the proposed formulation,
a procedure for model demonstration has been described. The proposed
methodology was supported by providing an example of data collected
and postprocessed by first-year undergraduate students. This work
will contribute to improving the pedagogical applications of chemiluminescent
reactions.
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