Bound states of massive particles, such as nuclei, atoms, or molecules, constitute the bulk of the visible world around us. By contrast, photons typically only interact weakly. We report the observation of traveling three-photon bound states in a quantum nonlinear medium where the interactions between photons are mediated by atomic Rydberg states. Photon correlation and conditional phase measurements reveal the distinct bunching and phase features associated with three-photon and two-photon bound states. Such photonic trimers and dimers possess shape-preserving wave functions that depend on the constituent photon number. The observed bunching and strongly nonlinear optical phase are described by an effective field theory of Rydberg-induced photon-photon interactions. These observations demonstrate the ability to realize and control strongly interacting quantum many-body states of light.

Realizing robust quantum phenomena in strongly interacting systems is one of the central challenges in modern physical science. Approaches ranging from topological protection to quantum error correction are currently being explored across many different experimental platforms, including electrons in condensed-matter systems, trapped atoms and photons. Although photon-photon interactions are typically negligible in conventional optical media, strong interactions between individual photons have recently been engineered in several systems. Here, using coherent coupling between light and Rydberg excitations in an ultracold atomic gas, we demonstrate a controlled and coherent exchange collision between two photons that is accompanied by a π/2 phase shift. The effect is robust in that the value of the phase shift is determined by the interaction symmetry rather than the precise experimental parameters, and in that it occurs under conditions where photon absorption is minimal. The measured phase shift of 0.48(3)π is in excellent agreement with a theoretical model. These observations open a route to realizing robust single-photon switches and all-optical quantum logic gates, and to exploring novel quantum many-body phenomena with strongly interacting photons.

Single-mode Josephson junction-based parametric amplifiers are often modeled as perfect amplifiers and squeezers. We show that, in practice, the gain, quantum efficiency, and output field squeezing of these devices are limited by usually neglected higher-order corrections to the idealized model. To arrive at this result, we derive the leading corrections to the lumped-element Josephson parametric amplifier of three common pumping schemes: monochromatic current pump, bichromatic current pump, and monochromatic flux pump. We show that the leading correction for the last two schemes is a single Kerr-type quartic term, while the first scheme contains additional cubic terms. In all cases, we find that the corrections are detrimental to squeezing. In addition, we show that the Kerr correction leads to a strongly phase-dependent reduction of the quantum efficiency of a phase-sensitive measurement. Finally, we quantify the departure from ideal Gaussian character of the filtered output field from numerical calculation of third and fourth order cumulants. Our results show that, while a Gaussian output field is expected for an ideal Josephson parametric amplifier, higher-order corrections lead to non-Gaussian effects which increase with both gain and nonlinearity strength. This theoretical study is complemented by experimental characterization of the output field of a flux-driven Josephson parametric amplifier. In addition to a measurement of the squeezing level of the filtered output field, the Husimi Q-function of the output field is imaged by the use of a deconvolution technique and compared to numerical results. This work establishes nonlinear corrections to the standard degenerate parametric amplifier model as an important contribution to Josephson parametric amplifier's squeezing and noise performance.