The Late Devonian was a protracted period of low speciation resulting in biodiversity decline, culminating in extinction events near the Devonian–Carboniferous boundary. Recent evidence indicates that the final extinction event may have coincided with a dramatic drop in stratospheric ozone, possibly due to a global temperature rise. Here we study an alternative possible cause for the postulated ozone drop: a nearby supernova explosion that could inflict damage by accelerating cosmic rays that can deliver ionizing radiation for up to ∼100 ky. We therefore propose that the end-Devonian extinctions were triggered by supernova explosions at ∼20 pc, somewhat beyond the “kill distance” that would have precipitated a full mass extinction. Such nearby supernovae are likely due to core collapses of massive stars; these are concentrated in the thin Galactic disk where the Sun resides. Detecting either of the long-lived radioisotopes Sm146 or Pu244 in one or more end-Devonian extinction strata would confirm a supernova origin, point to the core-collapse explosion of a massive star, and probe supernova nucleosynthesis. Other possible tests of the supernova hypothesis are discussed.

244Pu has recently been discovered in deep-sea deposits spanning the past 10 Myr, a period that includes two 60Fe pulses from nearby supernovae. 244Pu is among the heaviest r-process products, and we consider whether it was created in supernovae, which is disfavored by nucleosynthesis simulations, or in an earlier kilonova event that seeded the nearby interstellar medium with 244Pu that was subsequently swept up by the supernova debris. We discuss how these possibilities can be probed by measuring 244Pu and other r-process radioisotopes such as 129I and 182Hf, both in lunar regolith samples returned to Earth by missions such as Chang’e and Artemis, and in deep-sea deposits.

There is a wealth of data on live, undecayed 60Fe (t 1/2 = 2.6 Myr) in deep-sea deposits, the lunar regolith, cosmic rays, and Antarctic snow, which is interpreted as originating from the recent explosions of at least two near-Earth supernovae. We use the 60Fe profiles in deep-sea sediments to estimate the timescale of supernova debris deposition beginning ∼3 Myr ago. The available data admits a variety of different profile functions, but in all cases the best-fit 60Fe pulse durations are >1.6 Myr when all the data is combined. This timescale far exceeds the ≲0.1 Myr pulse that would be expected if 60Fe was entrained in the supernova blast wave plasma. We interpret the long signal duration as evidence that 60Fe arrives in the form of supernova dust, whose dynamics are separate from but coupled to the evolution of the blast plasma. In this framework, the >1.6 Myr is that for dust stopping due to drag forces. This scenario is consistent with the simulations in Fry et al. (2020), where the dust is magnetically trapped in supernova remnants and thereby confined around regions of the remnant dominated by supernova ejects, where magnetic fields are low. This picture fits naturally with models of cosmic-ray injection of refractory elements as sputtered supernova dust grains and implies that the recent 60Fe detections in cosmic rays complement the fragments of grains that survived to arrive on the Earth and Moon. Finally, we present possible tests for this scenario.

244 Pu has been discovered in deep-ocean deposits spanning the past 10 Myr, a period that includes two 60 Fe pulses from nearby supernovae. 244 Pu is among the heaviest r-process products, and we consider whether the 244 Pu was created in the supernovae, which is disfavored by model calculations, or in an earlier kilonova that seeded 244 Pu in the nearby interstellar medium, which was subsequently swept up by the supernova debris. We propose probing these possibilities by measuring other rprocess radioisotopes such as 129 I and 182 Hf in deep-ocean deposits and in lunar regolith.