Monotectic alloys show promising applications in wear-resistant automotive components, once these systems have remarkable self-lubricating properties that are of great interest for using in bearings. Much research has been devoted to better comprehend monotectic reactions. Some studies assume that the interphase spacing evolution in monotectic alloys follows the classical relationship used for eutectics or the dendritic growth relationship; however, some studies reported that the growth laws seem not to be valid for some cases. Because of that, obtaining single mathematical expressions that allow describing the development of solidification structures as a function of thermal parameters is very important. Based on the above, this chapter proposes a systematic analysis of the monotectic growth laws proposed in the literature and suggests exclusive growth laws as a function of solidification parameter for monotectic alloys solidified under different heat extracting configurations.