A structurally simple dielectric barrier discharge based mercury-free plasma UV-light source has been developed for efficient water disinfection. The source comprises of a dielectric barrier discharge arrangement between two co-axial quartz tubes with an optimized gas gap. The outer electrode is an aluminium baked foil tape arranged in a helical form with optimized pitch, while the inner electrode is a hollow aluminium metallic rod, hermetically sealed. Strong bands peaking at wavelengths 172 nm and 253 nm, along with a weak band peaking at wavelength 265 nm have been simultaneously observed due to plasma radiation from the admixture of xenon and iodine gases. The developed UV source has been used for bacterial deactivation studies using an experimental setup that is an equivalent of the conventional house-hold water purifier system. Deactivation studies for five types of bacteria, i.e., E. coli, Shigella boydii, Vibrio, Coliforms and Fecal coliform have been demonstrated with 4 log reductions in less than ten seconds.
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Recently, plasma produced by focusing femtosecond laser in gases has been introduced as an etching tool in materials processing. Proper control of the plasma in this application necessitates the apt understanding of the different morphological features of the plasma. In this contribution we show that, the plasma produced in air goes through several stages of morphological development – from ellipsoidal to spherical to toroidal plasma, whereas in argon, axial compression of an ellipsoidal plasma is observed. To explain this dissimilarity, we have quantified the temperature by emission spectroscopy (Planck analysis with Wien’s approximation). The evolution of temperature shows a triple exponential dependence in time which can be correlated with different stages of morphological changes of the plasma. Open Source Field Operation and Manipulation (OpenFOAM) simulations using experimentally determined temperature values show that – (i) the reverse pressure gradient propagates radially inwards and compresses the plasma in both air and argon and forms a localized high pressure zone at the center that generates a secondary pressure wave in air, but not in argon, and (ii) the baroclinic torque that is generated because of the Richtmyer-Meshkov instability, dominates the rate of vorticity in air, whereas effects of flow compressibility and velocity gradients dominate the vortices in argon. Knowledge of the initial state and the dynamics of the subsequent stages of the plasma formation can be utilized for control and optimization of laser-induced plasma applications.
Focusing of femtosecond laser pulses in gases can produce different gas breakdown phenomena depending on the focusing conditions: from simple optical breakdown like laser “sparks” to a nonlinear optical breakdown like filamentation. The dynamics of such plasmas after the pulse exposure is dependent on the energy deposited by the laser in the breakdown volume. Using a time- and position-dependent breakdown model, we estimate the breakdown volume and show that the energy deposited by the laser in this breakdown volume determines the characteristics of laser-induced plasma in the post-pulse exposure regime. Experimentally we find that for different focal lengths there exists a threshold value of the energy density beyond which a transition from an ellipsoidal shape to a spherical shape can be observed, followed by a toroidal expansion of the produced plasma. When electron density and electron temperature are expressed as a function of the energy density, deviations from the parabolic dependence on irradiance are observed. They imply additional ionization by multiphoton ionization in the plasma volume that occurs when the peak power of the laser pulse is above the critical power for self-focusing in air. The relevance of this experimental and theoretical study is to prevent undesired self-focusing conditions during material processing, a step toward well-controlled laser-plasma etching without laser ablation.
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