Biomarker‐ and compound‐specific carbon isotope analyses were used to compare oil samples recovered from Late Jurassic and Early to Middle Cretaceous reservoirs at South Pars and nearby fields in the Iranian portion of the Persian Gulf, and condensate samples associated with the super‐giant gas accumulation in Permo‐Triassic reservoirs at South Pars. The results indicate that all of the oil samples, including heavy oil from South Pars and oil from the Salman, Reshadat, Resalat and Balal fields, are genetically related. The most probable source rocks for these oils are Jurassic marine limestones or marls deposited under anoxic conditions. Based on the methyl phenanthrene index, source rock maturity was inferred to be equivalent to vitrinite reflectance values of about 0.8% Rc. The distribution and maturity pattern of the source rocks suggest migration from a depocentre located to the south, with inferred migration distances of up to 250 km. There is no genetic relationship between the heavy oil which has accumulated in Mesozoic reservoirs at South Pars and condensates which are associated with the super‐giant gas accumulation in Permo‐Triassic reservoirs there. Based on biomarker compositions, the condensates at South Pars appear to be derived from shaly marine or lacustrine source rocks deposited under dysoxic conditions. The δ13C values of short‐chain n‐alkanes and isoprenoids in condensate samples suggest a common source and an equal maturity for the source rocks. Pristane/n‐C17 versus phytane/n‐C18 characteristics are in agreement with published data for Silurian‐sourced condensates. High thermal maturities equivalent to 1.7% Rc are also consistent with a Palaeozoic (Silurian) source rock.
The Sab’atayn Basin is a major hydrocarbon province in Yemen. Important source rocks occur in Upper Jurassic units (Lam Member of the Madbi Formation, Sab’atayn Formation). Depositional environment, source potential and maturity of the source rocks were investigated using 60 cuttings samples from the Tagina South-1 Well. All samples were analysed for bulk parameters (total organic carbon (TOC), carbonate, sulphur, RockEval). A subset of samples was selected for biomarker analysis, pyrolysis-gas chromatography and isotope investigations. A carbonate-rich, euhaline, dysoxic to anoxic environment prevailed during deposition of the Lam Member. Bituminous shales within the overlying Sab’atayn Formation formed in a hypersaline, strictly anoxic depositional setting. Changes in the phytoplankton communities coincide with the outlined changes in the water body. Upward decreasing δ13C values suggest changes in carbon cycling due to changing redox conditions. The Lam Member, at least 500 m thick, is a good to very good source rock with an average TOC of 2.2%. The hydrogen index is controlled by maturity, but reaches 300 mg HC/g TOC in samples with low maturity (type II-III kerogen). The Lam Member produces sulphur-poor, paraffinic-naphthenic-aromatic low-wax oil. Bituminous shales in the Sab’atayn Formation contain up to 11% TOC and a type II (to III) kerogen (HI: up to 427 mg HC/g TOC). These shales are excellent sources for oil (and gas), but their source potential is limited by their relatively low thickness. Both, bituminous shales in the Sab’atayn Formation and the Lam Member are mature. The maturity of the deepest drilled part of the Lam Member is close to the zone of main oil generation. Numeric models show that Cenozoic heat flow is about 50 mW/m2. An increase in heat flow during Jurassic rifting is likely, but cannot be quantified. Major hydrocarbon generation occurred during Eocene–Oligocene times (assuming a Late Cretaceous heat flow of 50 mW/m2) or during both, Late Cretaceous and Eocene–Oligocene times (assuming a Late Cretaceous heat flow of 68 mW/m2).
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