The aim of this study was to assess the suitability of the atomic layer deposition method in terms of using it for 316 LVM (low carbon vacuum melt) steel surface modification that is used for blood‐contacting implants in determined technological conditions. As part of a suitability assessment of thin layer deposition technology, the performance of mechanical and physical properties testing was proposed. The investigation influences the evaluation of the analysed material in the cardiovascular system's behavior used for blood. 316 LVM stainless steel was the initial material to be tested. The 316 LVM steel was subjected to the following surface modifications: electrolytic polishing, chemical passivation and deposition of a silicon dioxide (SiO2) layer using the atomic layer deposition method. The layer was applied at a variable thickness depending on the atomic layer deposition process, at constant temperature. In terms of mechanical properties, the analyzing adhesion of applied layers to the metallic base and its hardness were examined. What is more, during the evaluation of physical properties, testing of surface wettability was performed, which has a fundamental significance in case of implants used in the cardiovascular system. The obtained results have direct impact on optimization process of SiO2 layers deposition with atomic layer deposition method on blood‐contacting implants, which surface was made of steel 316 LVM, there by resulting in their have a direct impact functional properties improvement.

The main goal of carried out tests were the impact of physicochemical properties of surface layers on the course of processes taking place on the surface of implants made of metallic biomaterials used in the bone system. As a precursor of ZnO, diethylzinc (DEZ) has been used, which reacted with water enabling the deposition of thin films. The chamber temperature was as follows—T = 200°–300 °C. The number of cycles was 500, 1000, and 1500. In the first stage, pitting corrosion test was carried out. Corrosion resistance has been tested under conditions simulating tissue environment. Moreover, the created layers were tested using electrochemical impedance spectroscopy (EIS). The conducted electrochemical tests showed the beneficial effect of the ZnO layer on the substrate made of 316 LVM steel, as evidenced by the obtained parameters describing the corrosion resistance. Furthermore, tests were performed on mechanical properties (scratch test), surface morphology (SEM and AFM method), and physical properties (wettability and thickness layers) for samples with different surface treatments. The investigations of the surface morphology of the applied ZnO layer using the ALD method showed a tendency to inherit the substrate independently of the used application parameters. On the other hand, the tests of adhesion to the substrate showed that the number of cycles of the application process has a fundamental impact on the adhesion of the applied layer to the substrate. Summarizing tests have clearly shown that the number of cycles and temperature in the case of the ZnO coating is significant and positively influences the increase of electrochemical, mechanical, and physical properties of layers.

The main purpose of the research was to analyze the influence of surface modification of the cobalt-based alloy used in dental prosthetics by applying zirconium oxide (ZrO2) layers using the ALD (Atomic Layer Deposition) method. The samples were made using the DMLS (Direct Metal Laser Sintering) technique, and their surfaces were prepared in accordance with the principles of removable partial dentures (RPDs). A 50 nm-thick zirconium oxide coating was applied to the prepared substrates. This paper deals with the issues of prosthetic stomatopathy, which is a complex of pathological changes occurring in approx. 40% of the Polish population using removable dentures. Often, these changes, occurring on the mucosa, are related to improper performance, allergic reactions or the multiplication of bacteria on the surface of partial dentures. An innovative method of surface modification was proposed, together with the analysis of its influence on the physicochemical properties of the alloy and the adhesion of bacteria to the surface.