Although the appropriate supply of nutrients has been extensively researched, more information is required on the effects of nutrients in treating gaseous volatile organic compounds (VOCs) in biofiltration. In this study, the effects of phosphorous and trace metals on gaseous toluene and methyl ethyl ketone (MEK) removal were investigated. The transfer of nutrients from the irrigation liquid to the packed bed, and the consumption and holding amount of nutrients in the packing material were observed during biofiltration. Under conditions of 20-24 s of empty bed residence time, MEK removal was 95% or more in all conditions of the biofiltration reactors, whereas toluene removal was affected by the operating conditions of the reactors. Consumption ratio of phosphorus to carbon was from 1.7 × 10 −4 to 1.1 × 10 −3 in the steady state of VOC removal under the conditions of this study. When gaseous VOC treatment was restarted after nine days of shutdown, a significant decline in toluene removal was observed by the reactor in which phosphorus supply was approximately one fifth of the amount in another reactor. Two types of irrigation systems, soaking and spraying, were compared and soaking irrigation achieved a more even distribution of nutrients held inside the packed bed. Soaking irrigation was expected to lead to higher VOC removal capacity by this distribution effect of nutrients, but toluene removal in the reactor with this irrigation was lower than that in the reactor with spraying irrigation. One of the possible reasons for this was the inhibition of nutrients transfer in the bottom part of the reactor. The trend of transfer in all ingredients from the irrigation liquid to the packed bed was synchronized on the whole; however, this transfer relatively tended to be high in nitrate and sodium and low in ammonium and phosphate.Implications: A major concern about using biofiltration systems to treat VOCs is the uncertainty regarding the appropriate nutrient supply to the filter bed to preserve microbial activity. This study showed that all the elements, except nitrogen, were retained sufficiently in the filter bed when a proper composition of nutrient solution was used for irrigation; however, phosphate addition may be needed when restarting a reactor from a prolonged period of shutdown. Distinct differences in the amount of transfer to the filter bed for different ingredients are probable, and may have to be taken into account when operating biofiltration reactors.

Studies on the relationship between moisture behavior and gaseous VOCs (Volatile Organic Compounds) removal efficiency of packed tower biofilters are limited. In this research, the nutrient holding capacity, moisture evaporation rate and gaseous toluene and MEK (Methyl Ethyl Ketone) removal efficiencies of bioreactors with porous synthetic resin as the packing material were simultaneously observed. The nutrient holding capacity in one of the reactors was higher than those of the other two because its packing layer was frequently supplied with a nutrient solution by soaking. This reactor exhibited the highest toluene removal efficiency. However, excessive biomass growth was observed in this reactor. The reactor with a less frequent supply of nutrient solution by soaking showed a slightly lower toluene removal efficiency, possibly due to lack of nutrients in the packing layer. The reactor that was fed with the nutrient solution by spraying it onto the packing layer (a common method for supplying moisture) had the lowest toluene removal efficiency, mainly because of the uneven distribution of nutrients. Moreover, the moisture evaporation rate in the packing layer during moisture supply and heat balance were determined.