The investigation of corrosion for carbon steel and galvanized steel has been conducted in the marine atmosphere of Eretan and Ciwaringin Districts, West Java Province. The exposure time of the field test was up to 200 days, and their corrosion rates are determined according to weight loss method. The objective of the work is to elucidate the corrosion behavior of those alloys which is affected by distances from coastline and environmental condition. The magnitude of corrosion rate for carbon steel was 20 times as high as that for galvanized steel in both districts The distance from coastline has significantly affected for the magnitude of corrosion rate, where that both alloys in Ciwaringin is lower than that in Eretan. The deposition of chloride ion in Eretan and Ciwaringin Districts were 4.305 mg/m2 day and 1.863 mg/m2 day, respectively, where the higher chloride ion can tend to increase the corrosion rates. Relative humidity (RH) which is over 60% has essential role for corrosion process as well as rainfall. The uniform corrosion attack was observed both alloys after exposure. The corrosion product phases of galvanized steel exhibits as zincite, hydrozincite and simonkolleite in Eretan as the typical coastline atmosphere phases but not in Ciwaringin. The formation of rust product for both metals lead the decrease of further corrosion attack due to the barrier between metal and environment. The usage of galvanized steel is remarkable to minimize corrosion attack compared to that of carbon steel in tropical coastline.
Proses dekomposisi dolomit menjadi MgO dan CaO merupakan proses penting mengingat kedua oksida tersebut banyak digunakan dalam berbagai aplikasi. Untuk melihat pengaruh suhu proses kalsinasi terhadap dekomposisi dolomit menjadi MgO dan CaO, maka dilakukan kalsinasi. Proses kalsinasi menggunakan tungku Muffle furnace dengan suhu sebesar 500 o C, 600 o C, 700 o C, 800 dan 900 o C. Sebanyak kurang lebih 100 gram/sampel dolomit dimasukkan dalam tungku dan dipanaskan dengan laju pemanasan 10 o C/menit pada berbagai suhu yang kemudian ditahan masing-masing selama 1 jam, 2 jam, 3 jam, 4 dan 5 jam. Produk kalsinasi kemudian ditimbang dan dikarakterisasi dengan X-Ray Diffraction (XRD) dan Scanning Electron Microscope (SEM). Hasil percobaan menunjukkan kalsinasi dolomit semakin meningkat seiring dengan kenaikkan suhu kalsinasi. Proses kalsinasi dolomit optimum tercapai pada suhu 900 o C selama 4 jam dengan pengurang berat mencapai 46,74 %. Berdasarkan perhitungan stoikiometri pengurangan berat 46,74 % menunjukkan bahwa 97,78 % dolomit terdekomposisi menjadi MgO dan CaO. Pembentukan fasa MgO dan CaO dari dolomit melalui dua tahapan yaitu tahapan pembentukan fasa MgO-CaCO 3 pada suhu 700 o C dan tahapan pembentukan CaO pada suhu 800 o C-900 o C. Kesimpulan yang didapatkan dari proses kalsinasi dolomit ini adalah peningkatan suhu kalsinasi dapat meningkatkan proses dekomposisi dolomit menjadi fasa MgO dan CaO.
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