Among the water-polluting substances, heavy metals stand out due to their carcinogenic and toxic effects on the creatures and environment. This study aimed to scrutinize the effectiveness of sewage sludge-based activated carbon in the removal of copper and cadmium from aqueous solutions in column study. Detection of breakthrough curves and related parameters was conducted by varying bed depths (3, 6, and 9 cm). The solution with an initial metal concentration (IMC) of 100 ppm was pumped to the column at a flow rate of 2 mL/min. In the process of copper removal, the breakthrough points for depths 3 cm, 6 cm, and 9 cm were achieved at 10 min, 15 min, and 60 min, respectively, whereas breakthrough points of similar depths in cadmium removal process were achieved at 5 min, 10 min, and 30 min, respectively. Adsorption kinetics were analyzed using the Adams–Bohart, Yoon–Nelson, and Thomas kinetics models. The Adams–Bohart model described only the initial part of breakthrough curves. The Thomas model represented the adsorption process with coefficients of determination (R2) ranging between 0.90–0.95 for cadmium removal and 0.89–0.96 for copper removal, while the coefficients of determination of Yoon–Nelson ranged between 0.89–0.94 for cadmium and 0.95–0.97 for copper. Yoon–Nelson was fitted well with copper removal data, while removal of cadmium data was best described by the Thomas model. This study demonstrated that using sewage sludge-based activated carbon to remove heavy metals is an alternative, more cost-effective option to reach the objectives of sustainable development.
This paper examines the economic and environmental impacts of district cooling systems (DCS) that are integrated with renewable energy sources and thermal energy storage (TES). Typically, a DCS offers a highly efficient and environmentally friendly alternative to traditional air conditioning systems, providing cool air to buildings and communities through a centralized system that uses chilled water. However, the integration of renewable energy and thermal energy storage into these systems can further increase their sustainability and efficiency, reducing their dependence on fossil fuels and improving their ability to handle fluctuations in demand. The goal of this paper is to provide a comprehensive review of the current state of the art of renewable energy-driven DCS with TES integrated and to highlight the benefits and challenges associated with these systems. Finally, the findings of this paper offer valuable insights into the potential for renewable energy-powered district cooling systems to contribute to a more sustainable and efficient built environment.
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