This work is devoted to the comparative study for the formation and dissociation of nitrogen oxides by the numerical simulation of turbulent combustion without premix in a combustion chamber having a cylindrical shape with two coaxial jets, two flames using the ANSYS fluent software16.0. The study focuses on the influence of the type of fuel on the composition of discharges in content with NOx, that is to say two cases are treated and compared. Turbulence is modeled by the k-ε model and the chemical aspect of combustion is treated by the PDF model for each flame. The calculation results relate to the characteristics of dynamic fields, temperature, the mass fractions of different species involved in the combustion process and the NOx prediction. The effect of the swirl is also tested in this study with a CFD prediction of non premixed swirling g flame. These results are compared with measurements and confrontations is satisfactory.