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BACKGROUND The recovery of metal ions from aqueous solutions for environmental preservation or resource saving requires the development of new sorbents with enhanced separation properties. A new process has been designed for the functionalization of magnetic chitosan microparticles with grafting of either amidoxime (AO‐AHC) or hydrazinyl amine (HZ‐AHC). Their sorption properties have been tested for the recovery of uranium(VI) and zirconium(IV) from aqueous solutions. RESULTS A wide range of analytical tools is used for characterizing not only the chemical modifications but also the interaction mode between the sorbent and target metal ions; including elemental analysis and titration, Fourier‐transform infrared (FTIR) spectroscopy and X‐ray photoelectron spectroscopy (XPS) characterizations, transmission electron microscopy (TEM) and scanning electron microscopy (SEM) observations, energy‐dispersive X‐ray spectroscopy (EDX) analysis and textural characterization. The optimum pH values were found in the range 4–5. The maximum sorption capacities depend on the metal and the kind of functionalization: up to 1.38 mmol U g−1 for AO‐AHC and up to 1.96 mmol Zr g−1 for HZ‐AHC. The small size of magnetic particles limits the contribution of diffusion mechanisms in the overall control of uptake kinetics and the equilibrium is reached within 40–60 min. Metal desorption is highly effective (almost quantitative over five successive cycles of sorption and desorption) using 0.3 M hydrochloric acid solutions. CONCLUSION AO‐AHC sorbent is more selective than HZ‐AHC in terms of separation of uranium(VI) from zirconium(IV), especially at pH close to 4. The results obtained in the treatment of acidic ore leachates confirm these trends. © 2019 Society of Chemical Industry

Catalytic methane decomposition (CMD) is a highly promising approach for the rational production of relatively COx-free hydrogen and carbon nanostructures, which are both important in multidisciplinary catalytic applications, electronics, fuel cells, etc. Research on CMD has been expanding in recent years with more than 2000 studies in the last five years alone. It is therefore a daunting task to provide a timely update on recent advances in the CMD process, related catalysis, kinetics, and reaction products. This mini-review emphasizes recent studies on the CMD process investigating self-standing/supported metal-based catalysts (e.g., Fe, Ni, Co, and Cu), metal oxide supports (e.g., SiO2, Al2O3, and TiO2), and carbon-based catalysts (e.g., carbon blacks, carbon nanotubes, and activated carbons) alongside their parameters supported with various examples, schematics, and comparison tables. In addition, the review examines the effect of a catalyst’s shape and composition on CMD activity, stability, and products. It also attempts to bridge the gap between research and practical utilization of the CMD process and its future prospects.

In the present work, the mass spectra of the bound states of heavy quarks cc-,bb-, and Bc meson are studied within the framework of the nonrelativistic Schrödinger’s equation. First, we solve Schrödinger’s equation with a general polynomial potential by Nikiforov-Uvarov (NU) method. The energy eigenvalues for any L- value is presented for a special case of the potential. The results obtained are in good agreement with the experimental data and are better than previous theoretical studies.

The structure and lean extinction of premixed liquefied petroleum gas–air flames seated on conductive perforated plates were examined experimentally, with focus on the effects of plate material, thickness, and hole diameter. The lean extinction limit was determined by gradually reducing the fuel-flow rate for a given air-flow rate, until extinction occurred. Flame structure was quantified by mapping the local mean temperature and species concentrations and by imaging the average visual length of the flame plume. Pyrometer measurements of the temperature of the upper plate surface were made to estimate the heat transfer through the plate. It was found that the flames stabilized on plates with higher thermal conductivity were shorter and more stable (i.e., have lower lean extinction limits). This was attributed to preheating of fresh reactant mixture by greater heat transfer through the plate. Increasing the hole diameter (percentage open area) was found to enhance flame stability by reducing the reactant jet velocity for a given flow rate of reactant mixture. Heat transfer through the plate deteriorated with increasing hole size. However, the positive effect of smaller jet velocity on flame stability overpowered the negative effect of reduced heat transfer, and the net result was enhanced stability with larger hole sizes. Plate thickness, on the other hand, was found to have a weak effect on flame stability and structure. Thicker plates showed slightly better stability characteristics because of greater heat transfer through them. Nonetheless, plate heat transfer did not affect flame stability as significantly as jet velocity did.