Due to the growing demand for hydrogen, the photocatalytic hydrogen production from alcohols present an intriguing prospect as a potential source of low-cost renewable energy. The noble metals (Ag, Au, Pd and Pt) deposited LaMnO3 nanocomposites were synthesized by a non-conventional green bio-reduction method using aqueous lemon peel extract, which acts as both reducing and capping agent. The successful deposition of the noble metals on the surface of LaMnO3 was verified by using powder XRD, FTIR, TEM, N2-physisorption, DR UV-vis spectroscopy, and XPS techniques. The photocatalytic activity of the synthesized nanocomposites was tested for photocatalytic H2 production under visible light irradiation. Different photocatalytic reaction parameters such as reaction time, pH, catalyst mass and reaction temperature were investigated to optimize the reaction conditions for synthesized nanocomposites. Among the synthesized noble metal deposited LaMnO3 nanocomposites, the Pt-LaMnO3 nanocomposite offered superior activity for H2 production. The enhanced photocatalytic activity of the Pt-LaMnO3 was found as a result from low bandgap energy, high photoelectrons generation and enhanced charge separation due to deposition of Pt nanoparticles. The effective noble metal deposition delivers a new route for the development of plasmonic noble metal-LaMnO3 nanocomposites for photocatalytic reforming of aqueous methanol to hydrogen.
Using hydrogen energy as an alternative renewable source of fuel is no longer an unrealized dream, it now has real-world application. The influence of nanomaterials on various aspects of hydrogen energy, such as hydrogen production, storage, and safety, is considerable. In this review, we present a brief overview of the nanomaterials that have been used as photocatalysts during hydrogen production. The use of nanomaterials and nanomaterial composites for hydrogen storage is also reviewed. The specific use of graphene and its associated nanocomposites, as well as the milestones reached through its application are elaborated. The need to widen the applicability of graphene and its allied forms for hydrogen energy applications is stressed in the future perspectives. Hydrogen energy is our future hope as an alternative renewable fuel, and graphene has the potential to become the future of hydrogen energy generation.
Due to significant advancements being made in the field of drug design, the use of topological descriptors remains the primary approach. When combined with QSPR models, descriptors illustrate a molecule’s chemical properties numerically. Numbers relating to chemical composition topological indices are structures that link chemical composition to physical characteristics. This research concentrates on the analysis of curvilinear regression models and degree-based topological descriptors for thirteen skin cancer drugs. The physicochemical characteristics of the skin cancer drugs are examined while regression models are built for computed index values. An analysis is performed for several significant results based on the acquired data.
Hydrogen is considered a good clean and renewable energy substitute for fossil fuels. The major obstacle facing hydrogen energy is its efficacy in meeting its commercial-scale demand. One of the most promising pathways for efficient hydrogen production is through water-splitting electrolysis. This requires the development of active, stable, and low-cost catalysts or electrocatalysts to achieve optimized electrocatalytic hydrogen production from water splitting. The objective of this review is to survey the activity, stability, and efficiency of various electrocatalysts involved in water splitting. The status quo of noble-metal- and non-noble-metal-based nano-electrocatalysts has been specifically discussed. Various composites and nanocomposite electrocatalysts that have significantly impacted electrocatalytic HERs have been discussed. New strategies and insights in exploring nanocomposite-based electrocatalysts and utilizing other new age nanomaterial options that will profoundly enhance the electrocatalytic activity and stability of HERs have been highlighted. Recommendations on future directions and deliberations for extrapolating information have been projected.
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