Free-Form-Gear (FFG) is a recently published title for a gear that has a curved path of contact and offers contact between a convex addendum and a concave dedendum during the meshing cycle. Based on this method of designing a gear pair, the path of contact can be altered to improve the way the gears mesh and slide against each other by only adjusting the maximum pressure angle and the involute curve parameter. The analytical investigations into this gear pair indicated that, when compared to the standard involute gear pair, the sliding velocity, meshing efficiency, contact, and fillet strengths are improved while the contact ratio is decreased. In this study, experimental stress analysis is conducted on various configurations of the tooth profile and tooth fillet shape for the proposed FFG and the standard involute gear to validate the analytical results. Since it is difficult to measure the contact stress for the gear specimens, the contact stresses at critical points are estimated using an effective computational technique based on photoelastic data and a numerical approach utilizing the nonlinear least squares method. At the fillet zone, isochromatic fringe patterns are used to directly measure the maximum fillet stress. Using addendum modification coefficients, the reduction in contact ratio for the proposed FFG is eliminated, and the results are then verified experimentally. Based on the experimental estimations, the finite element analyses are conducted using ABAQUS to simulate the examined gear specimens. Under the same loading conditions, the experimental, analytical, and numerical results have all been in good agreement.