The cause of heavy metal contamination in stream sediments is probably related to mining activities in Igun study area. Hence the degree of contamination of major and trace elements was carried out to ascertain environmental impact assessment of Igun and its environs, the geology of the study area shows that talc schist, quartzite, amphibolite and granite are the major rock types within the study area, while petrographic studies show quartz, microcline feldspar, biotite, muscovite and hornblende as the main mineral constituents. Total numbers of ten (10) stream sediment samples were collected, air dried at room temperature and analyzed using inductively coupled plasma mass spectrometry (ICP-MS) techniques. From the result of geochemical analysis of the stream sediment samples, the mean concentration for trace elements revealed that Manganese (Mn), Strontium (Sr), Zinc (Zn), Gold (Au) Nickel (Ni), Cobalt (Co) and Lead (Pb) have the mean values of 1704 ppm, 75.11 ppm, 55.80 ppm, 40.22 ppm, 26.15 ppm, 20.94 ppm, 10.60 ppm respectively. The contamination of metals was noticed from the geo accumulation index (Igeo), for stream sediments such as Nickel (0.1), copper (0.5), Manganese (0.6) with Igeo < 1 depicting that these metals are practically uncontaminated. Cobalt (0.1), Zinc (1.1) with Igeo number > 1 < 2 are moderately contaminated and Gold with Igeo of (9.6) indicate very high contamination. In conclusion the results shows that some part of the study area are contaminated and this includes Imoo (location 4), Owena (location 9) and Oke-Ipa (location 1) compared to other locations in the study area which are not contaminated.
Mining and related activities are sources of heavy metal contamination in streams, such as copper, zinc, cadmium, arsenic and lead . The study is focused on Ibodi, southwestern Nigeria which is located in the basement complex of Nigeria and it is to assess the stream sediments of Ibodi in order to decipher the environmental impact assessment of mining activities on the environment. A total of ten stream sediment were collected from the study area and its environs along major tributaries, air dried at room temperature, sieved with 75 micron sized sieve and analyzed in the laboratory using ICP-MS (inductively couple plasma mass spectrometry technique). The analytical results of the major elements analyses show that Iron oxide [Fe 2 O 3 ] has the highest major element composition, value ranging from 2.36% -10.61% with an average value of 5.262%. This highest concentration of Iron oxide was found in location 1, with a value of 10.61% and this can be attributed to the underlying geology of amphibolites' in the Ibodi study area, which are known to be rich in Iron as well as magnesium i.e ferromagnesian minerals. [Zn] is considerably high in the study area with the highest value found at location 4 of the study area indicating some level of enrichment of this metals within the study area, also [Rb], [Y] and [Sr] show some considerable enrichments within the study area. from the study of the environmental parameter such as box plot and Geo-accumulation indexes the values of the selected trace elements are all less than 1, meaning that all the selected trace metals in Ibodi study area have values less than zero and are in the negative zone. In order to determine the pollution status of the study area, the values of the elements when compared to the Muller classes of
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