In this study, the electrochemical corrosion behavior of copper was investigated in seawater collected from four different marine zones of Agadir coastal. These zones are different by the degree of pollution in order to study the effect of this pollution on the copper corrosion, especially the microbial pollution by sulfate reducing-bacteria (SRB). So, to prove this relationship, the microbiological analyses researching the SRB are realized. In parallel, the electrochemical impedance measurement and atomic absorption analysis are established to compare the microbiological evolution cycles with the electrochemical behavior of copper during the immersion period. In the results, we found a good correlation between the growth cycle of marine sulfate-reducing bacteria and the copper corrosion rate by the sulfur and extracellular polymeric substances (EPS) produced as bacteria metabolites. Additionally, this corrosion rate depends on the immersed time: it is maximal after the first or second month depending on the marine zone.
This work ultimately pays careful consideration to a method that respects the environment, and that can be developed across the accumulation of research to reduce the corrosion of metals in sea water. Extracts of Ziziphus lotus (wild jujube) were tested as a corrosion inhibitor of copper in sea water, using polarization methods and weight loss measurements. We also present by SEM the morphology of copper surface analyzed after immersion in inhibited and uninhibited electrolytes. The inhibition efficiency of Ziziphus lotus extracts was calculated and compared. We note good agreement between these methods. The obtained results revealed that the tested inhibitor significantly reduced the kinetics of the corrosion process of copper. Its efficiency increases with the concentration, and attained 93% at 5 g/L. The effect of temperature on the corrosion behavior of copper in natural sea water was also studied in the range of 293 K and 323 K, to determine thermodynamic data of activation.
The objective of this study was to monitor the bacteriological contamination of the seawater of the marine fisheries of the coastal Agadir, Morocco. The study was focused on the diagnosis on the pollution in heavy metals, such as cadmium, lead, and mercury in five zones: the port of Imi Ouaddar fish boarding (zone Z1), the old port of Agadir (zones Z2 and Z3), the port of Agadir Marina (zone Z4), and the estuary of Oued Souss (zone Z5). The analyses were done by testing physicochemical parameters (such as pH, temperature, dissolved oxygen, salinity and conductivity) as well as microbiological and atomic adsorption analyses. The experimental results showed that the values of the physicochemical parameters were almost the same in all zones, while the microbial conditions were different, in which this is due to the existence of heavy metals. The more heavy metal concentrations affected the condition of microbes in the sea water, confirmed by the number of Escherichia coli. This study demonstrated the importance of controlling concentration of heavy metals for better sustainability of environment.
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