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Polymeric carbon nitride (CN) is a fascinating metal-free photocatalyst for active solar energy conversion via water splitting. However, the photocatalytic activity of CN is significantly restricted by the intrinsic drawbacks of fast charge recombination because of incomplete polymerization. Herein, an in situ ionothermal molten salt strategy has been developed to construct polytriazine/heptazine based CN isotype heterojunctions from low cost and earth-abundant urea as the single-source precursor, with the purpose of greatly promoting the charge transfer and separation. The engineering of crystallinity and phase structure of CN has been attempted through facile tailoring of the condensation conditions in a molten salt medium. Increasing the synthetic temperature and eutectic salts/urea molar ratio leads to the formation of CN from bulk heptazine phase to crystalline polytriazine imide (PTI) phase, while CN isotype heterojunctions are in situ created at moderate synthetic temperature and salt amount. As evidenced by the measurements of UV–vis DRS and Mott–Schottky plots, the conduction band potentials can be tuned in a wide range from −1.51 to −0.96 V by controlling the synthetic temperature and salt amount, and the apparent band gap energies are reduced accordingly. The difference in band positions between PTI and heptazine phase CN enables the formation of CN heterojunctions, greatly promoting the separation of charge carriers. These metal-free CN heterojunctions demonstrate a well ordered needle-like morphology, and the optimal sample yields a remarkable hydrogen evolution rate (4813.2 μmol h–1 g–1), improved by a factor of 12 over that of bulk heptazine-based CN and a factor of 4 over that of PTI. The enhanced photocatalytic performance can be directly ascribed to the synergistic effect of the improved crystallinity with reduced structural defects, the decreased band gap energy with tunable band positions, and the efficient separation of charge carriers induced by the formation of heterostructures.

An efficient composite photocatalyst fabricated by dispersing ultrafine Fe2O3 nanocrystals onto g-C3N4 nanosheets via a facile deposition-precipitation method shows significantly enhanced photocatalytic performance under visible light irradiation.

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