The damping coefficient (tand) of wood flour filled polypropylene composites, having varying filler concentrations were measured using the free vibration decay of disk-shaped specimen, vibrating in flexural vibration mode. The damping coefficients decreased with the increase of filler load in composites. There was no significant difference in damping behavior of composites with and without compatiblizer at low filler level (upto 30%). At higher filler loading (>30%), composites with compatiblizer had lower damping coefficient suggesting improved interfacial adhesion between wood and polypropylene. The damping in composite is attributed to the damping because of the composite constituents and damping at the interface. The damping because of interface was estimated using a model and was found to increase with the increase in filler loading. At higher filler content, damping due to interface in composites with compatiblizer was significantly lower than in composites without compatiblizer suggesting a better interfacial adhesion between the wood filler and polypropylene matrix with compatiblizer.
Influence of polymer morphology on the inception and the growth of electrical trees in unfilled low density polyethylene (LDPE) as well as LDPE filled with 1, 3 and 5% by weight nanoalumina samples stressed with 50 Hz ac voltage has been studied. It is seen that there is a significant improvement in tree inception voltage with filler loading in LDPE filled with nanoparticles. Tree inception voltage increased with the filler loading up to 3% by weight nanoalumina loading and showed a reduction at 5% by weight loading. Change in tree growth patterns from branch to bush as well as a slower tree growth with increase in filler loading in LDPE alumina nanocomposites were observed. The degree of crystallinity and change in crystalline morphology induced by the presence of alumina nanoparticles in LDPE was studied using differential scanning calorimetry (DSC) and scanning electron microscopy (SEM). DSC results show a similar melting behaviour for both unfilled LDPE and LDPE nanocomposites. However, there is a reduction in the degree of crystallinity for LDPE filled with 5% by weight nanoalumina. An increase in lamellae packing with increase in filler loadings and a highly disordered spherulitic structure for LDPE filled with 5% by weight nanoalumina was observed from the SEM images. The slow propagation of tree growth as well as reduction in tree inception voltage with increase in filler loadings were attributed to the morphological changes observed in the LDPE nanocomposites.
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