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The risk assessment of heavy metal contamination was carried out in sediments of an urban tropical lake system (Akkulam-Veli) under threat from rapid unplanned urbanization and poor sewage management. Heavy metals were selected due to their persistent and bioaccumulative nature. Sequential extraction of the metals was carried out to resolve the sediments to their component phases. Well-established models were employed for risk analysis. The two pathways of contamination-ingestion and dermal contact-were considered for assessing risk. Risk Assessment Code of each metal was determined based on the lability of it in the different component phases. Cd was found to be the most hazardous metal by virtue of its high concentration in exchangeable and carbonate phases. Hazard indices of the metals were determined based on their total concentration in Akkulam-Veli (AV) Lake sediments. All heavy metals studied fall well below the threshold limit. However, Cr, Pb, and As, on account of their known toxicity, need to be monitored. Ni content in the lake system could potentially cause cancer to 134 adults in a population of one million. Concentrations of other metals are at carcinogenically safe limits. The study stresses the looming hazard faced by the Akkulam-Veli Lake system by heavy metal contaminants and the urgency in formulating remedial management plans.

Sediments are often reservoirs of contaminants in aquatic waterbodies, and their quality can be an indicator of the health of their ecosystems. Heavy metal pollution in sediments is highly significant because of their persistent and bioaccumulative nature. In this regard, sediment quality guidelines (SQG) are useful for categorizing sediment quality with respect to the contaminant level in them. An attempt was made in this study to assess the sediment quality of the Akkulam-Veli (AV) Lake system on the basis of guidelines that incorporate assessment scales that differ in their approaches. Some link threshold levels of heavy metal concentrations on the basis of their likelihood to cause adverse effects, while others classify the sediment concentration ranges that correspond to the degrees of toxicity caused by them. The sediment quality of the study area was assessed by combining the available guidelines to formulate two new approaches in this study. Based on this approach, AV Lake is highly polluted with respect to chromium (Cr), nickel (Ni) and lead (Pb), while arsenic (As) and cadmium (Cd) are non-polluting with a negligible potential for adverse effects.

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