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A laboratory-scale fluidized-bed reactor with an external aeration loop was used for nitrification of high-strength ammonium wastewater (up to 500 mg NH4-N/L). The results demonstrated that the system is capable of handling ammonium removal rates of up to 2.5 kg NH4-N/m3 x d, while removal efficiencies were as high as 98% and independent of the applied ammonium loading rates. Ammonium loading rates higher than 2.5 kg NH4-N/m3 x d resulted in decreased ammonium removal efficiency. The data show that near complete ammonium removal occurred at DO concentrations as low as 0.3-0.5 mg/L. However, the nitrite-nitrogen fraction in the effluent increased from 3.5% to 23.2% when the DO dropped from 1.0 mg/L to approximately 0.4 mg/L, respectively. The high specific removal rates in this system are one order of magnitude higher than that of suspended-growth systems. This can reduce the supplementary reactor volumes required for nitrification to less than 10% of that needed in conventional activated sludge systems. These results clearly indicate the potential economic gains that could be achieved through implementation of this technology.

Due to an increase in flows and loads and a new limit on effluent nitrate, the City of Merced was required to expand its wastewater treatment plant and provide improved denitrification. Process modeling and simulations were needed to design the improvements. To assure modeling accuracy, a wastewater characterization study was conducted, including intensive monitoring of influent, primary effluent, and secondary effluent and a Low F/M SBR bioassay. The results showed significant deviations in key modeling parameters from BioWin default values.

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