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Due to the instability and toxicity issues of lead/tin-based halide perovskites, lead-free metal halide perovskites have emerged as an attractive lead replacement for several semiconductor applications. Here, we present a bismuth (Bi)-based perovskite structure as a low-toxic and potentially substitutable alternative to lead-based perovskite solar cells. The synthesis and optical performance of MAPbI3, MA3Bi2I9Clx, and (MAPbI3:BiCl3) with ratios (of 10, 30, 50, 70)% as lead-free and low lead perovskite are prepared. The grinding technique is used as a green chemistry method compared to a typical reaction for scaling up production. The phase identification, crystallinity, thermal stability, optoelectronic properties, and nanoscale composition are comprised. The results showed that the prepared samples are enhanced in the visible absorption region and aligned well with previous literature. Besides, the bandgap energy for the mixed-structured perovskite, at a molar ratio of 10%, was reduced to 1.52 eV compared to 1.55 and 1.80 eV for MAPbI3, MA3Bi2I9Clx, respectively. At room temperature, the samples emitted intense photoluminescence in the 680–700 nm region. Our findings demonstrate the processability of bismuth perovskites, aiding in the development of high-performance low toxic perovskites by assisting in the refinement of materials and processing methods.

IGNAL-to-noise (S/N) ratio theory has proven to be useful in understanding, designing, and optimizing spectrophotometric measurement systems. Although a narrower spectral bandwidth does improve the resolution of closely spaced peaks, it also decreases the Signalto-noise ratio. The narrowest slit width should be used that will yield an acceptable Signalto-noise ratio. In this research, the wavelengths of peak absorbance of the holmium glass filter were determined to attain the optimum Signal-to-noise ratio accompanied with spectral bandwidths of 0.1 nm, 0.2 nm, 0.5 nm, 0.8 nm, 1 nm, 2 nm, 3 nm and 5 nm. The influence of spectral bandwidth on the Signal-to-noise ratio was by far the most important parameter affecting the location of the measured wavelengths of absorbance or transmittance of the sample.

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