This review collects a wide range
of initiatives and results that
expose the potential of the refineries to be converted into waste
refineries. Thus, they will use their current units for the valorization
of consumer society wastes (waste plastics and end-of-life tires in
particular) that are manufactured with petroleum derivatives. The
capacity, technological development, and versatility of fluid catalytic
cracking (FCC) and hydroprocessing units make them appropriate for
achieving this goal. Polyolefinic plastics (polyethylene and polypropylene),
the waxes obtained in their fast pyrolysis, and the tire pyrolysis
oils can be cofed together with the current streams of the industrial
units. Conventional refineries have the opportunity of operating as
waste refineries cofeeding these alternative feeds and tailoring the
properties of the fuels and raw materials produced to be adapted to
commercial requirements within the oil economy frame. This strategy
will contribute in a centralized and rational way to the recycling
of the consumer society wastes on a large scale. Furthermore, the
use of already existing and, especially, depreciated units for the
production of fuels and raw materials (such as light olefins and aromatics)
promotes the economy of the recycling process.
The deactivation of noble metal catalysts has been studied in the hydrocracking of the Light Cycle Oil (LCO) obtained as a byproduct in FCC units. The catalyst metallic functions are Pd, Pt, and PtÀPd, which are supported on acid materials of different porous structure and acidity (HY zeolite, Hβ zeolite, amorphous alumina, and an FCC catalyst). The reaction conditions are 350 °C; 50 bar; H 2 /LCO molar ratio (n H2 ), 8.9 mol H2 (mol LCO ) À1 ; space velocity (WHSV), 4 h À1 ; time on stream, 300 min. The roles of the metallic function, porous structure of the support, and, particularly, catalyst acidity in the deactivation by coke deposition have been studied. Deactivation leads the catalyst to a pseudostable state, with significant activity remaining when a support with high acidity is used (a HY zeolite with SiO 2 /Al 2 O 3 = 5) and a better performance of the PtÀPd metallic function.
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