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cis-[Cr(phen)2(dpp)(H2O)]2+ (phen = 1,10-orthophenanthroline; dpp = diphenyl phosphate) is prepared in aqueous solution and is remarkably stable over a wide range of pH. The dpp ligand is bound to the Cr(III) ion in an anti, unidentate fashion.

This work presents the synthesis and characterization of a series of substituted pyridylpentafluroporphyrins, including the separation of the cis- and trans-isomers, the latter being characterized by X-ray crystallography. The spectroscopic and electrochemical properties of the series are dependent on the number of electron withdrawing pentafluorophenyl substituent, but they do not depend on the symmetry of the molecule. Ongoing from the monosubstituted to the more substituted pentafluorophenyl porphyrin H2(MPyTFPP) derivative, the Soret bands are slightly red-shifted and their quantum fluorescence yields range from 0.035 to 0.046, consistent with the value of 0.045 for the fully substituted 5,10,15,20-tetrapentafluorophenylporphyrin (dichloromethane solutions). The redox potentials of the reductive processes of monoanion and dianion formation are also sensitive to the number of pentafluoro substituents, shifting 180 mV to more positive values for the P0/P-1process ongoing from the monopentafluoro to the tris-pentafluorophenyl substituted derivative.