Various strategies to chemically modify acenes for n-channel OFETs are discussed. Such strategies could also be useful for design of efficient n-type organic semiconductors based on other π-systems.

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Non‐alternant non‐benzenoid π‐conjugated polycyclic hydrocarbons (PHs) are expected to exhibit very different electronic properties from the all‐benzenoid PHs. Herein, we report the synthesis and physical properties of three azulene‐fused acene molecules (1, 2 and 3), which are isoelectronic to the pentacene, hexacene and heptacene, respectively. X‐ray crystallographic analysis, NMR spectra, and theoretical calculations reveal a localised aromatic backbone comprising all the six‐ and five‐membered rings while the seven‐membered ring remains non‐aromatic. They display properties of both azulene and acenes and are much more stable than the respective acenes. The dications of 1, 2 and 3 were formed by chemical oxidation. Notably, 32+ exhibited an open‐shell diradical character (y0=30.2 %) as confirmed by variable‐temperature NMR and ESR measurements, which can be explained by recovery of aromaticity of an 2,6‐anthraquinodimethane unit annulated with two aromatic tropylium rings.

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