CO2 capture of InOF-1 was enhanced 3.6-fold, at 1 bar and 30 °C, by confining EtOH within its pores. Direct visualisation by single crystal X-ray diffraction revealed that EtOH divides InOF-1 channels in wide sections separated by "bottlenecks" caused by EtOH molecules bonded to the μ2-OH functional groups of InOF-1.
The
water-stable material NOTT-401 was investigated for CO
2
capture under humid conditions. Water adsorption properties
of NOTT-401 were studied, and their correlation with CO
2
sequestration at different relative humidities (RHs) showed that
the CO
2
capture increased from 1.2 wt % (anhydrous conditions)
to 3.9 wt % under 5% RH at 30 °C, representing a 3.2-fold improvement.
Upon the removal of coordinated H2O and DMF molecules to the paddlewheel of MOP 4 (followed by FTIR), it showed very interesting CO2 capture properties at 196 K.
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