A two-dimensional mathematical model of dual-pulse laser ignition that self-consistently integrates Navier-Stokes, translational and vibrational energy, and neutral and charged species equations has been presented. The results showed that the ignition kernel dynamics depends on the shape and initial energy distribution in the energy spot created by the first ultraviolet laser pulse. The results also suggest that the ignition delay time and the flame kernel development depend on the laser intensity, vibrational-nonequilibrium, and initial electron number density. For the high initial degree of ionization, we have obtained ignition of the lean methane–air mixture with the equivalence ratio of 0.6. Vibrational-nonequilibrium taken into account by the Landau-Teller model leads to the slower ignition kernel growth and the significant increase in the ignition delay time. For the case modeled, a change in the overlap of the second laser with the focal point of the first laser pulse leads to the early split up of the kernel and the flame extinguishment.
Knowledge of optical effects accompanying hypersonic flight conditions is of critical importance to ensure reliable operation of on-board optical instrumentation. This paper presents results of calculations of scalar polarizability dependence on vibrational nonequilibrium in molecular nitrogen and oxygen. The non-equilibrium effects are evaluated on the basis of a semi-classical model for the molecular polarizability. It is shown that, depending on the vibrational and translational populations, changes in the scalar polarizability in excess of normal density and temperature scaling can be around 1%-5% at moderate gas temperatures and around 10% at high temperatures. The model was applied to predict the polarizability for non-equilibrium states in a nitrogen plasma formed by a single nanosecond pulse with different rise times.
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