The present study is concerned with the potential of high carbon, high silicon steel grades isothermally transformed to bainite at low temperature (< 300 °C). A first part gives an overview of design principles allowing very high strength and ductility to be achieved, while minimising transformation duration. Wear and fatigue properties are then investigated for over ten variants of such material, manufactured in the laboratory or industrially. The results are discussed against published data. Tensile strength above 2 GPa are routinely achieved, with, in one case, an exceptional and unprecedented total elongation of over 20%. Bainite plate thickness and retained austenite content are shown to be important factors in controlling the yield strength, though additional, non negligible parameters remain to be quantified. Rolling-sliding wear performances are found to be exceptional, with as little as 1% of the specific wear rate of conventional bainitised 100Cr6. It is suggested that this results from the decomposition of retained austenite in the worn layer, which considerably increases hardness and presumaby introduces compressive residual stresses. Fatigue performance were slightly improved over 100Cr6 for one of the two industrially produced material, but significantly lower otherwise. Factors controlling fatigue resistance require further investigations.
Specially designed steels with carbon contents from 0.6 to 1.0 wt.% were isothermally transformed at very low temperatures, between 220 and 270°C, in order to obtain a nano-structured bainitic microstructure. It is shown that the wear resistance in dry rolling-sliding of these nano-structured steels is significantly superior to that of bainitic steels transformed at higher temperatures with similar hardness values. In addition to the highly refined microstructure, the transformation under strain to martensite (TRIP effect), contributes to the plasticity of the nanoscaled steels, increasing surface hardness during testing, thus reducing the wear rate.
It is not the first time that a consortium of steel makers, end users and scientists ends up with unique approaches and developments in the physical metallurgy of steels. This paper reveals the scientific and technological developments of a consortium sharing a common intrigue and interest for a unique microstructure, nanostructured bainite. Also known as low temperature bainite, as its unique properties rely solely on the scale of the miscrostructure obtained by heat treatment at low temperature (150-350ºC). Careful design based on phase transformation theory, some well known metallurgy facts and the necessary industrial experience were the ingredients for a further step towards the industrialization of these microstructures.
The abrasive wear of carbide-free bainitic steel under dry rolling/sliding conditions has been studied. It is demonstrated that this nanostructure, generated by isothermal transformation at 200• C, has a resistance to wear that supersedes that of other carbide-free bainitic steels transformed at higher temperatures. The experimental results, in combination with a theoretical analysis of rolling/sliding indicates that under the conditions studied, the role of sliding is minimal, so that the maximum shear stresses during contact are generated below the contact surface. Thus, the hardness following testing is found to reach a maximum below the contact surface. The fine scale and associated strength of the structure combats wear during the running-in period, but the volume fraction, stability and morphology of retained austenite plays a significant role during wear, by work-hardening the surface through phase transformation into very hard martensite.
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