Urban expansion is a dynamic and complex phenomenon, often involving adverse changes in land use and land cover (LULC). This paper uses satellite imagery from Landsat-5 TM, Landsat-8 OLI, Sentinel-2 MSI, and GIS technology to analyse LULC changes in 2000, 2005, 2010, 2015, and 2020. The research was carried out in Opole, the capital of the Opole Agglomeration (south-western Poland). Maps produced from supervised spectral classification of remote sensing data revealed that in 20 years, built-up areas have increased about 40%, mainly at the expense of agricultural land. Detection of changes in the spatial pattern of LULC showed that the highest average rate of increase in built-up areas occurred in the zone 3–6 km (11.7%) and above 6 km (10.4%) from the centre of Opole. The analysis of the increase of built-up land in relation to the decreasing population (SDG 11.3.1) has confirmed the ongoing process of demographic suburbanisation. The paper shows that satellite imagery and GIS can be a valuable tool for local authorities and planners to monitor the scale of urbanisation processes for the purpose of adapting space management procedures to the changing environment.