When characterizing the space debris environment one important point is the identification of the physical properties of the space debris objects. Reflectance spectroscopy is a possible technique to study the surface material of these objects with observations from the ground. In this work the results collected from spectroscopy observations of space debris in orbit are presented. The observations were performed at the 1-meter ESA Space Debris Telescope (ESASDT) in Tenerife equipped with a spectrograph in the 450-960 nm wavelength range. A preliminary classification using three different categories purely based on the shape and appearance of the spectra was proposed. Two debris objects with high AMR could be successfully associated with materials analyzed in the laboratory. The results show that the two debris objects are probably pieces of Kapton MLI with 'gold' and 'silver' coating, respectively. Color indices were extracted from the spectroscopic measurements. For high AMR objects the colors seem to be consistent with the proposed classification in three categories. The B-R and R-I laboratory measurements of 'gold' and 'silver' MLI taken from the literature are comparable with the obtained results.

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Optical surveys for space debris in high-altitude orbits have been conducted since more than ten years. Originally these efforts concentrated mainly on the geostationary region (GEO). Corresponding observation strategies, processing techniques and cataloguing approaches have been developed and successfully applied. The ESA GEO surveys, e.g., resulted in the detection of a significant population of small-size debris and later in the discovery of high area-to-mass ratio objects in GEO-like orbits. Comparably less experience (both, in terms of practical observation and strategy definition) is available for eccentric orbits that (at least partly) are in the MEO region, in particular for the Molniya-type orbits.Different survey and follow-up strategies for searching space debris objects in highlyeccentric MEO orbits, and to acquire orbits which are sufficiently accurate to catalogue such objects and to maintain their orbits over longer time spans were developed. Simulations were performed to compare the performance of different survey and cataloguing strategies. Eventually, optical observations were conducted in the framework of an ESA study using ESA's Space Debris Telescope (ESASDT) the 1-m Zeiss telescope located at the Optical Ground Station (OGS) at the Teide Observatory at Tenerife, Spain.Thirteen nights of surveys of Molniya-type orbits were performed between January and August 2013. Eventually 255 surveys were performed during these thirteen nights corresponding to about 47 hours of observations. In total 30 uncorrelated faint objects were discovered. On average one uncorrelated object was found every 100 minutes of observations. Some of these objects show a considerable brightness variation and have a high area-to-mass ratio as determined in the orbit estimation process.