In this study, Erianthus arundinaceus energy grass was examined
by conducting hydrothermal carbonization
(HTC) using a laboratory-scale autoclave in the temperature range
of (180–240 °C) and the retention time of (0–120
min). The parent material and hydrochars were investigated in terms
of mass yield, proximate and elemental analyses, the higher heating
value (HHV), X-ray diffraction, Fourier transform infrared, and X-ray
fluorescence (XRF) analyses. Furthermore, CO2 gasification
was conducted on the pyrolysis char prepared from the parent material
and the hydrochars using thermogravimetric analysis. It was found
that increasing the HTC temperature and residence time caused the
mass yield to decrease and the HHV to increase. Hydrochar crystallinity
increased with HTC temperature up to 210 °C as a result of the
deformation of the amorphous components, while under 240 °C,
the crystallinity declined from its peak at 210 °C due to the
commencing of cellulose degradation. The XRF analysis showed that
the alkali index was increased due to increasing temperature and residence
time. Gasification reactivity of the pyrolyzed hydrochar prepared
at 180 °C was enhanced due to longer residence time (120 min),
while those from very short residence time (0 min) showed a weaker
reactivity than the parent material. Changing the HTC temperature
showed minimal effect on the reactivity. At higher HTC temperature
(240 °C), the catalytic activity was restricted by the highly
ordered structure. This was not the case at 180 °C and long residence
time of 120 min, where the reactivity was mainly controlled by the
increased minerals.
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