The aim of this research is to contribute to the literature in the field, filling the gap concerning how logistics impacts the relationship between pollution and economic complexity worldwide. Investigating the weights of the multiple dimensions of logistic performance appears very relevant and strengthens the literature in the field in terms of studies carried out in abnormal times that impact society and the economy at their core. From a methodological standpoint, this study uses a structural equations approach, revealing a complex mediating chain linking pollution with logistics performances. Our results show that logistics is a net contributor to pollution and further investment in supply chain green innovation is needed to achieve the objectives of green logistics.