Information about heavy metal concentrations in food products and their dietary intake are essential for assessing the health risk of local inhabitants. The main purposes of the present study were (1) to investigate the concentrations of Zn, Cu, Pb, and Cd in several vegetables and fruits cultivated in Baia Mare mining area (Romania); (2) to assess the human health risk associated with the ingestion of contaminated vegetables and fruits by calculating the daily intake rate (DIR) and the target hazard quotient (THQ); and (3) to establish some recommendations on human diet in order to assure an improvement in food safety. The concentration order of heavy metals in the analyzed vegetable and fruit samples was Zn > Cu > Pb > Cd. The results showed the heavy metals are more likely to accumulate in vegetables (10.8-630.6 mg/kg dw for Zn, 1.4-196.6 mg/kg dw for Cu, 0.2-155.7 mg/kg dw for Pb, and 0.03-6.61 mg/kg dw for Cd) than in fruits (4.9-55.9 mg/kg dw for Zn, 1.9-24.7 mg/kg dw for Cu, 0.04-8.82 mg/kg dw for Pb, and 0.01-0.81 mg/kg dw for Cd). Parsley, kohlrabi, and lettuce proved to be high heavy metal accumulators. By calculating DIR and THQ, the data indicated that consumption of parsley, kohlrabi, and lettuce from the area on a regular basis may pose high potential health risks to local inhabitants, especially in the area located close to non-ferrous metallurgical plants (Romplumb SA and Cuprom SA) and close to Tăuții de Sus tailings ponds. The DIR for Zn (85.3-231.6 μg/day kg body weight) and Cu (25.0-44.6 μg/day kg body weight) were higher in rural areas, while for Pb (0.6-3.1 μg/day kg body weight) and Cd (0.22-0.82 μg/day kg body weight), the DIR were higher in urban areas, close to the non-ferrous metallurgical plants SC Romplumb SA and SC Cuprom SA. The THQ for Zn, Cu, Pb, and Cd was higher than 5 for <1, <1, 12, and 6% of samples which indicates that those consumers may experience major health risks.
Background: Metal transfer along the food chain has raised concerns about impacts on human health due to dietary exposure to low but chronic concentrations. Soil–forage–milk–consumer is a short food chain through which metals are able to reach an organism. Methods: Pb, Cu, Cd, and Zn were determined in water, soil, forage, and milk samples collected from free-range cattle farms situated near Baia Mare, Romania. The soil-to-forage (TFsf) and forage-to-milk (TFfm) transfer factors for metals and the health risk for three population groups (females, males, and children) through the consumption of milk containing low levels of metals were assessed. Results: TFsf indicated that the uptake capabilities of the metals from soil to forage were in the following order: Zn > Cd > Cu > Pb. TFfm indicated a lack of metal accumulation through forage ingestion. Estimated daily (EDI) and provisional tolerable weekly (PTWI) intake values revealed a minimal exposure of the population to those metals through milk consumption. A noncarcinogenic hazard index indicated that milk consumption from local markets does not pose any risk for human health; however, the average cancer risk showed a high potential carcinogenic risk. Conclusions: The consumption of milk produced by small local farmers does not pose noncarcinogenic risks. More extended studies should be carried out in order to identify the potential carcinogenic risk caused by the low levels of metals in the milk consumed.
The Cd, Cu, Pb and Zn contents in home-grown crops in a former mining district were determined in order to evaluate the non-carcinogenic long-term potential health risk related to crop consumption. The potential health risk was investigated by estimating the daily intake and the hazard quotients. For all crop categories, the daily intake and the target hazard quotient were below the threshold values for Cd, Cu, and Zn. The daily intake of Pb exceeded the oral reference dose, while the target hazard quotient for vegetables was above 1, indicating a potential health risk. The total target hazard quotient for the individual metals decreased in the following order: Pb>Cd>Cu>Zn. This study confirmed that the daily consumption of crops grown in contaminated soils could pose health risks to humans.
Large-scale flood risk assessment is essential in supporting national and global policies, emergency operations and land-use management. The present study proposes a cost-efficient method for the large-scale mapping of direct economic flood damage in data-scarce environments. The proposed framework consists of three main stages: (i) deriving a water depth map through a geomorphic method based on a supervised linear binary classification; (ii) generating an exposure land-use map developed from multi-spectral Landsat 8 satellite images using a machine-learning classification algorithm; and (iii) performing a flood damage assessment using a GIS tool, based on the vulnerability (depth–damage) curves method. The proposed integrated method was applied over the entire country of Romania (including minor order basins) for a 100-year return time at 30-m resolution. The results showed how the description of flood risk may especially benefit from the ability of the proposed cost-efficient model to carry out large-scale analyses in data-scarce environments. This approach may help in performing and updating risk assessments and management, taking into account the temporal and spatial changes in hazard, exposure, and vulnerability.
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