Widespread anoxic events affected the Tethys Ocean during the Mesozoic. The Ocean Anoxic Event 1a (Early Aptian), expressed as the Selli Level or Goguel Level (GL) in European basins. The GL was deposited in the French Vocontian Basin, a semi-enclosed basin connected to the Tethys Ocean. This study presents an integrated approach (Rock Eval, clay minerals, grain-size, inorganic geochemistry and molecular biomarkers), applied to four sections in the basin distributed along a proximal-distal transect. This study shows that the GL was perturbed by turbidites.In particular, the results demonstrate: (a) a homogeneous redox status of the basin that experienced oxic to suboxic conditions, according to trace element distributions and (b) low organic matter contents (total organic carbon ca 1 wt%) in the three sections where turbiditic deposits are observed. The distal, condensed section exhibits the highest organic matter contents (total organic carbon >3 wt%). In addition, the presence of gammacerane and isorenieratene derivatives in the distal sections suggests that the water-column was intermittently stratified, with hypoxia developing in the photic zone. This stratification did not result from strong surface productivity but more likely from: (a) limited renewal of deep water in the basin; (b) reputedly high surface-water palaeotemperatures during the Early Aptian; and (c) the influx of waters, possibly depleted in free oxygen and in some dissolved trace elements, into the basin. The turbiditic inputs, in addition to organic matter dilution in the sediments and a brief rupture of the water-column stratification in the proximal areas of the basin, ventilated the sea floor and more specifically re-oxidized the sedimentwater interface as well as underlying sediments. Such episodes of benthic re-oxygenation could have altered the long-term palaeoredox record, even in the distal sections where reducing conditions prevailed during deposition. In the area deprived of turbiditic input, sedimentary condensation, coupled with low oxygen conditions, furthered organic matter preservation and concentration.
The Marnes Bleues Formation from the Vocontian Basin (Southeastern France) shows many organic rich levels, some concomitant to oceanic anoxic events OAE1a and OAE1b. These organic-rich levels are scattered through a thick homogeneous succession of marls, poor in organic matter (OM). Through a multi-parameter approach, the organic-rich levels from the Aptian-Albian were characterized. Our results show that all OM-rich levels exhibit variable characteristics, such as OM nature (marine vs. continental), sedimentation and accumulation rates, redox conditions, surface-water productivity and relative sea level, but they all show low to modest enrichments in OM. Furthermore, all the levels share in common the fact that they formed under conditions of normal to low productivity and oxic to suboxic conditions. Thus, our results strongly suggest that, in the absence of high productivity and anoxic bottom conditions, the other factors reputed to favor OM accumulation only led to sporadic and low enrichments in organic contents. It is as if such factors could only enhance OM accumulation but could not induce it alone. What was true for the Vocontian Basin may be extended to other settings, regardless of their time of deposition or location.
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