The demand for nanostructured materials can increase exponentially due to the miniaturization of devices and their potential application in different areas, such as electronic and medicine. Therefore, high production rates are essential for making nanomaterials commercially available. When electrospinning (ES) and solution blow spinning (SBS) are employed for producing ceramic nanostructures, the solution injection rate can influence the morphology without, however, supply the real ceramic production rate. In this work, complex superconducting YBa2Cu3O7-x wires were prepared by using the SBS technique. We also show that the morphology can be controlled by varying the injection rate of the polymer solution and the production rate is 4.7 to 33 times higher than the rates of equivalent ceramics produced by ES. Additionally, we also suggest the term Ceramic Production Rate to refer to the production rate of ceramic structures.
The microstructure and magnetic characterizations of non-woven, fabric-like YBa2Cu3Oy (YBCO) nanofiber mats are reported. The samples were produced by solution blow spinning (SBS), starting from a sol-gel solution of the precursor materials in polyvinylpyrrolidone. In the present work, the nanowire network samples were morphologically characterized by scanning electron microscopy, and the superconducting properties were measured by magnetometry. An interesting feature is the appearance of a paramagnetic Meissner effect (PME) when field-cooling, firstly verified in that sort of sample. The PME appears only in very small applied magnetic fields, which is similar to previous observations of the PME on an artificially granular YBCO thin film, but distinctly different from bulk samples investigated in the literature. Thus, we explain the PME by flux trapping within the voids of the nanoporous structure of the nanofiber mats.
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