Abstract:The current work presents the preparation of polypropylene (PP) foams by the extrusion process, focusing on the influence of the foaming agent and nucleating agent on the microstructure of the foams. Sodium bicarbonate alone and also its mixture with citric acid were used as the chemical blowing agents. Expanded graphite nanoparticle and talc were also used as the nucleating agents. Great differences were found in terms of the foam structure depending on the type of nucleating and blowing agents. Using expanded graphite nucleating agent instead of talc resulted in foams with higher cell densities and more uniform cellular structures. Moreover, the foams including the mixed blowing agents exhibited higher cell densities and upper expansion ratio.

Bubble growth during polymeric foam production by a physical nucleating agent is a result of rapid gas phase separation in a polymer/gas solution media. The dynamics of bubble growth is thought to be influenced by the material properties and processing conditions. However, the degree of effectiveness of each parameter has not been evaluated in earlier studies. In this work, a simplified single bubble growth in a polymeric media was modeled to specify the critical parameters affecting the bubble growth phenomenon. The predicted bubble growth profile was compared with some experimental data reported in the literature. The model was able to predict the observed bubble growth profile with acceptable precision. Therefore, it was applied to investigate the effect of each physical property of the polymer, i.e. viscosity, surface tension and diffusion coefficient as well as processing conditions, i.e. temperature and pressure release rate on the bubble growth profile. Furthermore, the impact of each factor was clarified.