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Purpose The purpose of this study is to provide the description of a computational methodology to model the combined propulsive systems of hydrogen propelled air-breathing scramjet vehicles and to evaluate the pollutant and climate-changing emissions. Design/methodology/approach Emissions indexes of nitrogen oxide (EINO) and water vapour released by the air turbo rocket (ATR) and dual mode ramjet (DMR) engines of the STRATOFLY air-breathing, hypersonic scramjet vehicle, propelled by hydrogen/air were evaluated. ATR engine operation was assessed for several cruise conditions in both subsonic and supersonic flight regimes in Ecosimpro software, which is an object-oriented thermodynamic design and simulation platform. ATR combustor inlet flow conditions play a key role in the computation of species mass fractions, and these conditions are highly dependent on turbomachinery performance and engine flight regime. A propulsive operational database was created by varying mass flow rates of fuel and flight conditions such as cruise speed and altitude to investigate possible engine operations. The all-inlet conditions in this map are provided to the Cantera-Python chemical/combustion chemistry solver implementing a specially designed and formulated 0D kinetic-thermodynamic methodology successfully used to model and simulate the electric spark ignition required to activate the combustion process of the reacting mixture in the ATR combustion chambers, whereas the coupled aero-thermodynamic/aero-propulsive 0D/1D code i.e. Scramjet PREliminary Aerothermodynamic Design (SPREAD), designed and developed by the Italian Aerospace Research Centre (CIRA) was used for DMR calculations. Results show low emissions of NO according to the optimized design of the ATR; on the other hand, a tuning of operational conditions is needed for DMR, with its complete re-design to be more conclusive. Analogously, the released amount of water vapour is in good agreement with the required combustion efficiency and the expected propulsive performance. Findings Results show low emissions of NO according to the optimized design of the ATRs; on the other hand, a tuning of operational conditions is needed for DMR, with its complete re-design to be more conclusive. Analogously, the released amount of water vapour is in good agreement with the required combustion efficiency and the expected propulsive performance. Originality/value Applications of innovative 0D/1D chemical kinetic methodology and in-house codes.

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