No abstract

Capturing high spatial resolution imagery is becoming a standard operation in many agricultural applications. The increased capacity for image capture necessitates corresponding advances in analysis algorithms. This study introduces automated raster geoprocessing methods to automatically extract strawberry (Fragaria × ananassa) canopy size metrics using raster image analysis and utilize the extracted metrics in statistical modeling of strawberry dry weight. Automated canopy delineation and canopy size metrics extraction models were developed and implemented using ArcMap software v 10.7 and made available by the authors. The workflows were demonstrated using high spatial resolution (1 mm resolution) orthoimages and digital surface models (2 mm) of 34 strawberry plots (each containing 17 different plant genotypes) planted on raised beds. The images were captured on a weekly basis throughout the strawberry growing season (16 weeks) between early November and late February. The results of extracting four canopy size metrics (area, volume, average height, and height standard deviation) using automatically delineated and visually interpreted canopies were compared. The trends observed in the differences between canopy metrics extracted using the automatically delineated and visually interpreted canopies showed no significant differences. The R2 values of the models were 0.77 and 0.76 for the two datasets and the leave-one-out (LOO) cross validation root mean square error (RMSE) of the two models were 9.2 g and 9.4 g, respectively. The results show the feasibility of using automated methods for canopy delineation and canopy metric extraction to support plant phenotyping applications.

The emulsion polymerization of styrene initiated by potassium persulfate catalyzed by Ag(I) and/or ferrous ions Fe (II) was studied. It was found that silver ions in conjunction with potassium persulfate accelerate the polymerization of styrene. Ferrous ions reduce the polymerization rate by termination reaction with primary radicals. Both silver ions and ferrous ions act as transfer agents with the result of lowering of the average molecular weight of the polymer.

The emulsion polymerization of styrene initiated by potassium persulfate catalyzed by Ti+3 ions was studied. Two sources of Ti+3 ions were used: the titanium trichloride and titanium sulfate. It was found that the titanium ions used in conjunction with potassium persulfate decrease both the reaction rate and the average molecular weight. An even greater drop of reaction rate was noted when chlorine anions (TiCl3) were present. The presence of these ions had a stabilizing effect on the polydispersity.