BackgroundNowadays, study and application of modified membranes for water treatment have been considered significantly. The aim of this study was to prepare and characterize a polysulfone (PSF)/graphene oxide (GO) nanocomposite membrane and to evaluate for arsenate rejection from water.Materials and methodsThe nanocomposite PSF/GO membrane was fabricated using wet phase inversion method. The effect of GO on the synthesized membrane morphology and hydrophilicity was studied by using FE-SEM, AFM, contact angle, zeta potential, porosity and pore size tests. The membrane performance was also evaluated in terms of pure water flux and arsenate rejection.ResultsATR-FTIR confirmed the presence of hydrophilic functional groups on the surface of the prepared GO. FE-SEM micrographs showed that with increasing GO content in the casting solution, the sub-layer structure was enhanced and the drop like voids in the pure PSF membrane changed to macrovoids in PSF/GO membrane along with increase in porosity. AFM images indicated lower roughness of modified membrane compared to pure PSF membrane. Furthermore, contact angle measurement and permeation experiment showed that by increasing GO up to 1 wt%, membrane hydrophilicity and pure water flux were increased. For PSF/GO-1, pure water flux was calculated about 50 L/m2h at 4 bar. The maximum rejection was obtained by PSF/GO-2 about 83.65 % at 4 bar. Moreover, it was revealed that arsenate rejection depended on solution pH values. It was showed that with increasing pH, the rejection increased.ConclusionsThis study showed that application of GO as an additive to PSF casting solution could enhance the membrane hydrophilicity, porosity, flux and arsenate rejection.
Despite the vast improvements of cell therapy in spinal cord injury treatment, no optimum protocol has been developed for application of neural stem/progenitor cells. In this regard, the present meta-analysis showed that the efficacy of the neural stem/progenitor cell (NSPC) transplantation depends mainly on injury model, intervention phase, transplanted cell count, immunosuppressive use, and probably stem cell source. Improved functional recovery post NSPC transplantation was found to be higher in transection and contusion models. Moreover, NSPC transplantation in acute phase of spinal injury was found to have better functional recovery. Higher doses (>3×10(6)cell/kg) were also shown to be optimum for transplantation, but immunosuppressive agent administration negatively affected the motor function recovery. Scaffold use in NSPC transplantation could also effectively raise functional recovery.
Continuous monitoring of drinking water quality is essential in terms of heavy metals and toxic substances. The general objective of this study were to determine the concentration of heavy metals in drinking water of Khorramabad city and to determine the water quality indices (The heavy metal pollution index and heavy metal evaluation index). According to the city map, 45 points were selected for drinking water sampling through the city distribution system. The results of this study showed that the average concentration of heavy metals such as Zn, Pb, Cd, Cr, and Cu were 47.01 μg/l, 3.2 μg/l, 0.42 μg/l, 5.08 μg/l, and 6.79 μg/l, respectively. The HPI and HEI (water quality indices) for Zn, Pb, Cd, Cr, and Cu were 46.58, 46.58, respectively. According to the indices, the city drinking water quality is good in terms of heavy metals.
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