Porous substrates have the ability to transport liquids not only laterally on their open surfaces but also transversally through their thickness. Directionality of the fluid transport can be achieved through spatial wettability patterning of these substrates. Different designs of wettability patterns are implemented herein to attain different schemes (modes) of three-dimensional transport in a high-density paper towel, which acts as a thin porous matrix directing the fluid. All schemes facilitate precise transport of metered liquid microvolumes (dispensed as droplets) on the surface and through the substrate. One selected mode features lateral fluid transport along the bottom surface of the substrate, with the top surface remaining dry, except at the initial droplet dispension point. This configuration is investigated in further detail, and an analytical model is developed to predict the temporal variation of the penetrating drop shape. The analysis and respective measurements agree within the experimental error limits, thus confirming the model's ability to account for the main transport mechanisms.
Surfaces with extreme wettability (too low, superhydrophobic; too high, superhydrophilic) have attracted considerable attention over the past two decades. Titanium dioxide (TiO2) has been one of the most popular components for generating superhydrophobic/hydrophilic coatings. Combining TiO2 with ethanol and a commercial fluoroacrylic copolymer dispersion, known as PMC, can produce coatings with water contact angles approaching 170°. Another property of interest for this specific TiO2 formulation is its photocatalytic behavior, which causes the contact angle of water to be gradually reduced with rising timed exposure to UV light. While this formulation has been employed in many studies, there exists no quantitative guidance to determine or tune the contact angle (and thus wettability) with the composition of the coating and UV exposure time. In this article, machine learning models are employed to predict the required UV exposure time for any specified TiO2/PMC coating composition to attain a certain wettability (UV-reduced contact angle). For that purpose, eight different coating compositions were applied to glass slides and exposed to UV light for different time intervals. The collected contact-angle data was supplied to different regression models to designate the best method to predict the required UV exposure time for a prespecified wettability. Two types of machine learning models were used: (1) parametric and (2) nonparametric. The results showed a nonlinear behavior between the coating formulation and its contact angle attained after timed UV exposure. Nonparametric methods showed high accuracy and stability with general regression neural network (GRNN) performing best with an accuracy of 0.971, 0.977, and 0.933 on the test, train, and unseen data set, respectively. The present study not only provides quantitative guidance for producing coatings of specified wettability, but also presents a generalized methodology that could be employed for other functional coatings in technological applications requiring precise fluid/surface interactions.
The Stirling engine is an external heat engine, which is considered as the best option for extracting work from concentrated solar power applications. The most prominent characteristics of the engine are low noise, vibration, and emissions besides reflexivity of usage with any kind of heat source such as solar, biomass, industrial heat, etc. In the present paper, the STE-1008 gamma-type Stirling engine had been analyzed by using an isothermal model to demonstrate the failure of the model in analyzing the STE-1008 considering it firstly as an engine and secondly as a cryocooler. The energy equation had been used to demonstrate the disability of the isothermal model in achieving a successful thermal analysis for engine performance. In addition, a MATLAB code had been developed to check the credibility of the isothermal model in the estimation of the engine thermal parameters. The findings of the isothermal analysis revealed that the heat exchangers are unnecessary. But, in reality; all the necessary heat transfer occur within the heat exchangers rather than in the working space boundaries. Therefore, that is invalid conclusion. However, Schmidt's theory is capable of capturing the essential engine features superbly. In particular, it is capable of capturing the fundamental interplay between the mechanically restricted movement of the engine components as well as the thermodynamic cycle which is obtained from this theory.
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