The steel industry is among the highest carbon-emitting industrial sectors. Since the steel production process is already exhaustively optimized, alternative routes are sought in order to increase carbon efficiency and reduce these emissions. During steel production, three main carbon-containing off-gases are generated: blast furnace gas, coke oven gas and basic oxygen furnace gas. In the present work, the addition of renewable hydrogen by electrolysis to those steelworks off-gases is studied for the production of methane and methanol. Different case scenarios are investigated using AspenPlusTM flowsheet simulations, which differ on the end-product, the feedstock flowrates and on the production of power. Each case study is evaluated in terms of hydrogen and electrolysis requirements, carbon conversion, hydrogen consumption, and product yields. The findings of this study showed that the electrolysis requirements surpass the energy content of the steelwork’s feedstock. However, for the methanol synthesis cases, substantial improvements can be achieved if recycling a significant amount of the residual hydrogen.

Within integrated steelmaking industries significant research efforts are devoted to the efficient use of resources and the reduction of CO2 emissions. Integrated steelworks consume a considerable quantity of raw materials and produce a high amount of by-products, such as off-gases, currently used for the internal production of heat, steam or electricity. These off-gases can be further valorized as feedstock for methane and methanol syntheses, but their hydrogen content is often inadequate to reach high conversions in synthesis processes. The addition of hydrogen is fundamental and a suitable hydrogen production process must be selected to obtain advantages in process economy and sustainability. This paper presents a comparative analysis of different hydrogen production processes from renewable energy, namely polymer electrolyte membrane electrolysis, solid oxide electrolyze cell electrolysis, and biomass gasification. Aspen Plus® V11-based models were developed, and simulations were conducted for sensitivity analyses to acquire useful information related to the process behavior. Advantages and disadvantages for each considered process were highlighted. In addition, the integration of the analyzed hydrogen production methods with methane and methanol syntheses is analyzed through further Aspen Plus®-based simulations. The pros and cons of the different hydrogen production options coupled with methane and methanol syntheses included in steelmaking industries are analyzed.

The European Steel industry is spending considerable efforts in order to improve the socio-economic and environmental sustainability of its processes by promoting any development, which can increase efficiency and lower the environmental impact of the steel production processes. In particular, the European iron and steel sector is strongly committed toward the reduction of energy consumptions and CO2 emissions. Process gases are a very valuable resource: possibilities exist to consider these gases as an intermediate by-product for the production of other valuable energy carriers or products with an associated environmental benefit. Therefore, the process gas networks, especially inside the integrated steelworks, have a fundamental function, as they allow meeting the demand of many processes and producing energy through dedicated facilities. They can also support the production processes by internal electric energy generation and often by supplying energy outside the plant boundaries. On the other hand, such networks are very complex systems interacting with many different production steps and the management of such complex systems is a very difficult task, where many often-counteracting factors need to be jointly taken into account. This paper presents the first outcomes of the research project entitled “Optimization of the management of the process gas network within the integrated steelworks (GASNET)”, which aims at developing a Decision Support System helping the energy managers and other concerned technical personnel to implement an optimized off-gases management and exploitation considering environmental and economic objectives. A series of Key Performance Indicators has been elaborated, in order to monitor the efficiency of the gas management and the objectives of the optimization have been defined. The overall structure of the project and the ongoing work will also be outlined in the paper.

The valorization of integrated steelworks process off-gases as feedstock for synthesizing methane and methanol is in line with European Green Deal challenges. However, this target can be generally achieved only through process off-gases enrichment with hydrogen and use of cutting-edge syntheses reactors coupled to advanced control systems. These aspects are addressed in the RFCS project i3upgrade and the central role of hydrogen was evident from the first stages of the project. First stationary scenario analyses showed that the required hydrogen amount is significant and existing renewable hydrogen production technologies are not ready to satisfy the demand in an economic perspective. The poor availability of low-cost green hydrogen as one of the main barriers for producing methane and methanol from process off-gases is further highlighted in the application of an ad-hoc developed dispatch controller for managing hydrogen intensified syntheses in integrated steelworks. The dispatch controller considers both economic and environmental impacts in the cost function and, although significant environmental benefits are obtainable by exploiting process off-gases in the syntheses, the current hydrogen costs highly affect the dispatch controller decisions. This underlines the need for big scale green hydrogen production processes and dedicated green markets for hydrogen-intensive industries, which would ensure easy access to this fundamental gas paving the way for a C-lean and more sustainable steel production.

The implementation of Industrial Symbiosis and Energy Efficiency is linked to the ongoing technological development. New technologies can lead to an increased up-take of these concepts, which affect all areas of process industries and involve the whole workforce. The present paper describes part of the work developed in the early stage of a current Erasmus+ project entitled “Skills Alliance for Industrial Symbiosis: A Cross-sectoral Blueprint for a Sustainable Process Industry (SPIRE-SAIS)”. Such project aims at developing an industry-driven and proactive skills strategy to assist the implementation and exploitation of Industrial Symbiosis and Energy Efficiency across the energy-intensive industrial sectors, which are represented by the association of Sustainable Process Industry through Resource and Energy Efficiency (SPIRE). The main aspects of the current state of implementation of Industrial Symbiosis and Energy Efficiency in European process industries are analyzed. In addition, upcoming techniques and developments are taken into account for the main considered sectors, e.g., Iron and Steel, Chemical, Non-ferrous Metals, Mineral, Water, Ceramics, and Cement. Achieved results on implementation of technologies and practices based on Industrial Symbiosis and Energy Efficiency, as well as new challenges coming from their accomplishments are considered. Companies’ perceptions on future implementation of Industrial Symbiosis and Energy Efficiency are explored, together with possible barriers resulting in implementation practices and expected solutions to satisfy related ongoing and future skill demands.