Multiphase coexistence has attracted significant interest in recent years because its control has entailed a significant breakthrough for the piezoelectric activity enhancement of lead-free piezoelectric oxides. However, the comprehension of...
Defective few-layered graphene mesostructures
(DFLGMs) are produced
from graphite flakes by high-energy milling processes. We obtain an
accurate control of the generated mesostructures, as well as of the
amount and classification of the structural defects formed, providing
a functional material for microwave absorption purposes. Working under
far-field conditions, competitive values of minimum reflection loss
coefficient (RLmin) = −21.76 dB and EAB = 4.77 dB
are achieved when DFLGMs are immersed in paints at a low volume fraction
(1.95%). One step forward is developed by combining them with the
excellent absorption behavior that offers amorphous Fe73.5Si13.5B9Cu1Nb microwires (MWs),
varying their filling contents, which are below 3%. We obtain a RLmin improvement of 47% (−53.08 dB) and an EAB enhancement
of 137% (4 dB) compared to those obtained by MW-based paints. Furthermore,
a f
min tunability is demonstrated, maintaining
similar RLmin and EAB values, irrespective of an ideal
matching thickness. In this scenario, the Maxwell-Garnet standard
model is valid, and dielectric losses mainly come from multiple reflections,
interfacial and dielectric polarizations, which greatly boost the
microwave attenuation of MWs. The present concept can remarkably enhance
not only the MW attenuation but can also apply to other microwave
absorption architectures of technological interest by adding low quantities
of DFLGMs.
In the quest for effective gas sensors for breath analysis, magnetoelastic resonance-based gas sensors (MEGSs) are remarkable candidates. Thanks to their intrinsic contactless operation, they can be used as non-invasive and portable devices. However, traditional monitoring techniques are bound to slow detection, which hinders their application to fast bio-related reactions. Here we present a method for real-time monitoring of the resonance frequency, with a proof of concept for real-time monitoring of gaseous biomarkers based on resonance frequency. This method was validated with a MEGS based on a Metglass 2826 MB microribbon with a polyvinylpyrrolidone (PVP) nanofiber electrospun functionalization. The device provided a low-noise (RMS = 1.7 Hz), fast (<2 min), and highly reproducible response to humidity (Δf = 46–182 Hz for 17–95% RH), ammonia (Δf = 112 Hz for 40 ppm), and acetone (Δf = 44 Hz for 40 ppm). These analytes are highly important in biomedical applications, particularly ammonia and acetone, which are biomarkers related to diseases such as diabetes. Furthermore, the capability of distinguishing between breath and regular air was demonstrated with real breath measurements. The sensor also exhibited strong resistance to benzene, a common gaseous interferent in breath analysis.
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